New synthesis and structural characterization of O-aryldithiophosphato and O-alkyldithiophosphato nickel complexes with diphosphine ligands

被引：24

作者：

Li, Yu-Long ^{[1
]}

Xie, Bin ^{[1
]}

Zou, Li-Ke ^{[1
]}

Lin, Xiao ^{[1
]}

Yang, Yi ^{[1
]}

Zhu, Sha-sha ^{[1
]}

Wang, Tao ^{[1
]}

机构：

[1] Sichuan Univ Sci & Engn, Key Lab Green Catalysis, Higher Educ Inst Sichuan, Sch Chem & Pharmaceut Engn, Zigong 643000, Sichuan, Peoples R China

来源：

POLYHEDRON | 2014年 / 67卷

关键词：

Dithiophosphate; Diphosphine; Synthesis; X-ray crystallography; CROSS-COUPLING REACTION; MOLECULAR-STRUCTURE; ARYLBORONIC ACIDS; ARYL MESYLATES; DONOR LIGANDS; CRYSTAL; BIARYLS; CHLOROARENES; PHOSPHORUS; CHEMISTRY;

D O I：

10.1016/j.poly.2013.09.041

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

O-aryldithiophosphato and O-alkyldithiophosphato nickel complexes with diphosphine ligands have been synthesized by treatment of (diphosphine)NiCl2 {diphosphine = dppe (Ph2PCH2CH2PPh2), dppv (Ph2PCH = CHPPh2). dppb (1,2-(Ph2P)(2)C6H4)} with dithiophosphoric acid (RO)(2)P(S)SH (R = CH2CH3, CH2CH2Ph). The synthesis route is found to be an efficient pathway to prepare the O-alkyldithiophosphato and O-alkyldithiophosphato nickel complexes. All the complexes [Ni(S2P{O}OCH2CH2Ph)(dppe)] (1), [Ni(S2P{O}OCH2CH2Ph)(dppv)] (2), [Ni(S2P{O}OCH2CH2Ph)(dppb)] (3), [Ni(S2P{O}OCH2CH3)(dppe)] (4), [Ni(S2P{O}OCH2CH3)(dppv)] (5) have been fully characterized by elemental analysis and IR, H-1, C-13, P-31 NMR spectroscopies. In addition the molecular structures of 1-4 were established by X-ray crystallography. Crown Copyright (C) 2013 Published by Elsevier Ltd. All rights reserved.

引用

页码：490 / 494

页数：5

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