Electron-Transfer Processes in Highly-Correlated Electron Systems of Thiazyl Radicals

被引：17

作者：

Awaga, Kunio ^{[1
,2
,3
]}

Nomura, Kenji ^{[1
,2
]}

Kishida, Hideo ^{[4
]}

Fujita, Wataru ^{[1
,2
]}

Yoshikawa, Hirofumi ^{[1
,2
]}

Matsushita, Michio M. ^{[1
,2
]}

Hu, Laigui ^{[1
,2
]}

Shuku, Yoshiaki ^{[1
,2
]}

Suizu, Rie ^{[1
,2
]}

机构：

[1] Nagoya Univ, Res Ctr Mat Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[2] Nagoya Univ, Dept Chem, Grad Sch Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[3] Nagoya Univ, CREST, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[4] Nagoya Univ, Dept Appl Phys, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2014年 / 87卷 / 02期

关键词：

TRANSFER PHASE-TRANSITION; CHARGE-TRANSFER COMPLEX; MULTIDIMENSIONAL NETWORK STRUCTURES; SOLID-STATE PROPERTIES; ORGANIC THIN-FILMS; MAGNETIC-PROPERTIES; DITHIAZOLYL RADICALS; CRYSTAL-STRUCTURES; METAL-COMPLEXES; TRANSFER SALTS;

D O I：

10.1246/bcsj.20130248

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heterocyclic thiazyl radicals possess unique chemical and physical properties as building blocks for molecule-based conductors and magnetic materials. They do not need protecting groups on their molecular skeletons, and the lack of such substituents permits close packing in the solid state. Moreover, thiazyl radical solids often involve a multidimensional network consisting of pi-pi overlaps and S center dot center dot center dot N contacts. The electronic structures of the thiazyl radicals can be compared to highly-correlated electron systems. In this account, we describe various electron-transfer processes in the solids of the thiazyl radicals, which manifest themselves by external stimuli such as temperature change, electric field, and photoillumination.

引用

页码：234 / 249

页数：16

共 141 条

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