Characterization of stabilized porous magnetite core-shell nanogel composites based on crosslinked acrylamide/sodium acrylate copolymers

Stabilized and dispersed superparamagnetic porous nanogels based on sodium acrylate (AA-Na) and acrylamide (AM) in a surfactant-free aqueous system were synthesized via solution polymerization at room temperature. The formation of magnetite nanoparticles was confirmed and their properties characterized using Fourier transform infrared spectroscopy. Extensive characterization of the magnetic polymer particles using transmission electron microscopy (TEM), dynamic light scattering and zeta potential measurements revealed that Fe3O4 nanoparticles were incorporated into the shells of poly(AM/AA-Na). The average particle size was 5-8nm as determined from TEM. AM/AA-Na nanoparticles with a diameter of about 11nm were effectively assembled onto the negatively charged surface of the as-synthesized Fe3O4 nanoparticles via electrostatic interaction. Crosslinked magnetite nanocomposites were prepared by in situ development of surface-modified magnetite nanoparticles in an AM/AA-Na hydrogel. Scanning electron microscopy was used to study the surface morphology of the prepared composites. The morphology, phase composition and crystallinity of the prepared nanocomposites were characterized. Atomic force microscopy and argon adsorption-desorption measurements of Fe3O4.AM/AA indicated that the architecture of the polymer network can be a hollow porous sphere or a solid phase, depending on the AA-Na content. (c) 2013 Society of Chemical Industry