An efficient strategy for photocatalytic hydrogen peroxide production over oxygen-enriched graphitic carbon nitride with sodium phosphate

Photocatalytic hydrogen peroxide (H2O2) production is a promising strategy to replace the tradi-tional production processes; however, the inefficient H2O2 productivity limits its application. In this study, oxygen-rich g-C3N4 with abundant nitrogen vacancies (OCN) was synthesized for photocata-lytic H2O2 production. X-ray photoelectron spectroscopy and Fourier-transform infrared spectros-copy indicated that oxygen-containing functional groups (-COOH and C-O-C) were obtained. Elec-tron paramagnetic resonance confirmed the successful introduction of nitrogen vacancies. OCN exhibited efficient photocatalytic H2O2 production performance of 1965 mu mol L-1 h-1 in air under visible-light irradiation. The high H2O2 production was attributed to the enhanced adsorption of oxygen, enlarged specific surface area, and promoted carrier separation. An increased H2O2 produc-tion rate (5781 mu mol L-1 h-1) was achieved in a Na3PO4 solution. The improved performance was attributed to the changed reactive oxygen species. Specifically, the adsorbed PO43- on the surface of the OCN promoted the transfer of holes to the catalyst surface. center dot O2- obtained by O2 reduction react-ed with adjacent holes to generate 1O2, which could efficiently generate H2O2 with isopropanol. Ad-ditionally, PO43-, as a stabilizer, inhibited the decomposition of H2O2.(c) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.