Electrocatalytic oxidation of sucrose: Analysis of the reaction products

被引：25
|
作者：
Parpot, P
Kokoh, KB
Belgsir, EM
Leger, JM
Beden, B
Lamy, C
机构：
[1] UNIV POITIERS,LAB CHIM 1,URA CNRS 350,F-86022 POITIERS,FRANCE
[2] UNIV MINHO,DEPT QUIM,P-4719 BRAGA,PORTUGAL
来源：
JOURNAL OF APPLIED ELECTROCHEMISTRY | 1997年 / 27卷 / 01期
关键词：
D O I：
10.1023/A:1026458714202
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The analysis of sucronic acids produced by the electrocatalytic oxidation of sucrose is described. The main reaction products, 1'-monocarboxylic and 6-monocarboxylic acids of sucrose, were identified by means of gas and liquid chromatography, mass spectrometry, NMR and i.r. spectroscopy, and acid hydrolysis. The quantitative analysis of reaction products other than the sucronic acids was realized by ionic chromatography (Dionex), whereas that of the sucronic acids was carried out using their acid hydrolysis products.
引用
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页码：25 / 33
页数：9
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