Hybrid Organic-Inorganic Block Copolymer Nano-objects from RAFT Polymerization-Induced Self-Assembly

被引：24

作者：

Deng, Yuanming ^{[1
,2
,3
,4
]}

Yang, Cangjie ^{[1
]}

Yuan, Conghui ^{[1
]}

Xu, Yiting ^{[1
]}

Bernard, Julien ^{[2
,3
]}

Dai, Lizong ^{[1
]}

Gerard, Jean-Francois ^{[2
,3
]}

机构：

[1] Xiamen Univ, Coll Mat, Key Lab Fire Retardant Mat Fujian Prov, Xiamen 361005, Peoples R China

[2] INSA Lyon, IMP, F-69621 Villeurbanne, France

[3] CNRS, UMR 5223, F-69621 Villeurbanne, France

[4] Shenzhen Univ, Shenzhen Key Lab Special Funct Mat, Coll Mat Sci & Engn, Shenzhen 518060, Peoples R China

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2013年 / 51卷 / 21期

基金：

中国国家自然科学基金;

关键词：

block copolymers; O; I hybrid nano-objects; Polyhedral oligmeric silsesquioxane; reversible addition-fragmentation chain transfer; Self-assembly; OLIGOMERIC SILSESQUIOXANE POSS; INCORPORATING POLYHEDRAL OLIGOSILSESQUIOXANE; TRANSFER RADICAL POLYMERIZATION; SPONTANEOUS VESICLE FORMATION; DISPERSION POLYMERIZATION; AMPHIPHILIC TELECHELICS; TRIBLOCK COPOLYMERS; DILUTE-SOLUTION; IN-SITU; POLYMERS;

D O I：

10.1002/pola.26872

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A simple route to organic-inorganic (O/I) nano-objects with different morphologies through polymerization-induced block copolymer self-assembly is described. The synthetic strategy relies on the chain-extension of polyhedral oligomeric silsesquioxanes (POSS)-containing macro-CTA (PMAiBuPOSS(13) and PMAiBuPOSS(19)) with styrene at 120 degrees C in octane, a selective solvent of the POSS-containing block. The polymerization system was proven to afford a plethora of O/I nano-objects, such as spherical micelles, cylindrical micelles, and vesicles depending on the respective molar masses of the PMAiBuPOSS and polystyrene (PS) blocks. The cooling procedure was also proven to be a crucial step to generate particles with a unique morphology. (c) 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 4558-4564

引用

页码：4558 / 4564

页数：7

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