An iron(III) tetradentate monoamido complex as a nonheme iron-based peroxidase mimetic

被引：17

作者：

Hitomi, Yutaka ^{[1
]}

Hiramatsu, Kazuaki ^{[1
]}

Arakawa, Kengo ^{[1
]}

Takeyasu, Toshiyuki ^{[1
]}

Hata, Masashi ^{[1
]}

Kodera, Masahito ^{[1
]}

机构：

[1] Doshisha Univ, Fac Sci & Engn, Dept Mol Chem & Biochem, Kyoto 6100321, Japan

来源：

DALTON TRANSACTIONS | 2013年 / 42卷 / 36期

关键词：

O BOND-CLEAVAGE; HYDROGEN-PEROXIDE; C-H; ALKANE HYDROXYLATION; OXIDATION REACTIONS; CATALYTIC-ACTIVITY; FE; INTERMEDIATE; H2O2; DIHYDROXYLATION;

D O I：

10.1039/c3dt51483h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A mononuclear iron(III) complex of a noncyclic tetradentate mono-amido ligand, Fe(III)mpaq, catalyses the oxidation of Orange II, guaiacol, ABTS and Amplex Red with H2O2 in aqueous solutions at neutral pH. Under identical conditions, other structurally related nonheme iron complexes showed only negligible activities.

引用

页码：12878 / 12882

页数：5

共 31 条

[1] A density functional study of O-O bond cleavage for a biomimetic non-heme iron complex demonstrating an FeV-intermediate [J].

Bassan, A ;

Blomberg, MRA ;

Siegbahn, PEM ;

Que, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (37) :11056-11063

[2]

Binstead R. A., 1998, SPECFIT GLOBAL ANAL, V27515

[3] Mechanistic Investigations of the Reaction of an Iron(III) Octa-Anionic Porphyrin Complex with Hydrogen Peroxide and the Catalyzed Oxidation of Diammonium-2,2′-azinobis(3-ethylbenzothiazoline-6-sulfonate) [J].

Brausam, Ariane ;

Eigler, Siegfried ;

Jux, Norbert ;

van Eldik, Rudi .

INORGANIC CHEMISTRY, 2009, 48 (16) :7667-7678

[4] REACTIONS OF HYDROPEROXIDES WITH METALLOTETRAPHENYLPORPHYRINS IN AQUEOUS-SOLUTIONS [J].

BRUICE, TC .

ACCOUNTS OF CHEMICAL RESEARCH, 1991, 24 (08) :243-249

[5] Characterization of an FeIII-OOH species and its decomposition product in a bleomycin model system [J].

Bukowski, MR ;

Zhu, SR ;

Koehntop, KD ;

Brennessel, WW ;

Que, L .

JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 2004, 9 (01) :39-48

[6] FeIII-TAML-catalyzed green oxidative degradation of the azo dye Orange II by H2O2 and organic peroxides:: products, toxicity, kinetics, and mechanisms [J].

Chahbane, Naima ;

Popescu, Delia-Laura ;

Mitchell, Douglas A. ;

Chanda, Arani ;

Lenoir, Dieter ;

Ryabov, Alexander D. ;

Schramm, Karl-Werner ;

Collins, Terrence J. .

GREEN CHEMISTRY, 2007, 9 (01) :49-57

[7] Total degradation of fenitrothion and other organophosphorus pesticides by catalytic oxidation employing Fe-TAML peroxide activators [J].

Chanda, Arani ;

Khetan, Sushil K. ;

Banerjee, Deboshri ;

Ghosh, Anindya ;

Collins, Terrence J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (37) :12058-12059

[8] Stereospecific alkane hydroxylation by non-heme iron catalysts:: Mechanistic evidence for an FeV=O active species [J].

Chen, K ;

Que, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (26) :6327-6337

[9] A functional mimic of natural peroxidases: synthesis and catalytic activity of a non-heme iron peptide hydroperoxide complex [J].

Choma, CT ;

Schudde, EP ;

Kellogg, RM ;

Robillard, GT ;

Feringa, BL .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1998, (04) :769-773

[10] TAML oxidant activators: A new approach to the activation of hydrogen peroxide for environmentally significant problems [J].

Collins, TJ .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (09) :782-790

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