Characterisation of Germanium Monohalides by Solid-State NMR Spectroscopy and First Principles Quantum Chemical Calculations

被引：4

作者：

Hanson, Margaret A. ^{[1
]}

Schnepf, Andreas ^{[2
]}

Terskikh, Victor V. ^{[3
]}

Huang, Yining ^{[1
]}

Baines, Kim M. ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

[2] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany

[3] Natl Ultrahigh Field NMR Facil Solids, Ottawa, ON K1A 0R6, Canada

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2013年 / 66卷 / 10期

基金：

加拿大自然科学与工程研究理事会; 加拿大创新基金会;

关键词：

METALLOID CLUSTER COMPOUNDS; OXIDE MATERIALS; QUADRUPOLAR; CHLORINE; CHEMISTRY; BROMIDE; GLASSES;

D O I：

10.1071/CH13122

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Germanium(I) monohalides are useful starting materials to synthesise small, well defined germanium nanoclusters. However, due to the amorphous nature of solid GeBr and GeCl, details of their solid-state structures remain largely unknown. We investigate the arrangement within these novel binary materials using Cl-35, Br-79, and Ge-73 solid-state NMR spectroscopy at 21.1 T and first principles quantum chemical calculations in order to suggest a possible model for the structure.

引用

页码：1202 / 1210

页数：9

共 50 条

[41] Solid-State NMR Spectroscopy on Complex Biomolecules
Renault, Marie
Cukkemane, Abhishek
Baldus, Marc
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (45) : 8346 - 8357
[42] Solid-state covariance NMR spectroscopy: An update
Takeda, Kazuyuki
ANNUAL REPORTS ON NMR SPECTROSCOPY, VOL 100, 2020, 100 : 153 - 201
[43] Automated projection spectroscopy in solid-state NMR
Klein, Alexander
Vasa, Suresh K.
Linser, Rasmus
JOURNAL OF BIOMOLECULAR NMR, 2018, 72 (3-4) : 163 - 170
[44] SOLID-STATE NMR-SPECTROSCOPY OF FATS
COLQUHOUN, IJ
GRANT, A
AGRICULTURE, FOOD CHEMISTRY AND THE CONSUMER, VOLS 1 AND 2: THE CONSUMER AND FOOD, ANALYTICAL FOOD CHEMISTRY AND AGRICULTURAL PRODUCTION, BIOTECHNOLOGY AND BIOASSAYS - IMPACT OF TECHNOLOGY ON FOOD QUALITY, FOOD CHEMISTRY AND QUALITY ASSURANCE, 1989, : 668 - 672
[45] Solid-state NMR spectroscopy of mercury compounds
Bowmaker, GA
Harris, RK
Oh, SW
COORDINATION CHEMISTRY REVIEWS, 1997, 167 : 49 - 94
[46] A thermometer for nonspinning solid-state NMR spectroscopy
Beckmann, PA
Dybowski, C
JOURNAL OF MAGNETIC RESONANCE, 2000, 146 (02) : 379 - 380
[47] Solid-state NMR spectroscopy in pharmaceutical sciences
Li, Mingyue
Xu, Wei
Su, Yongchao
TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2021, 135
[48] Solid-state NMR spectroscopy of microcrystalline proteins
Kraus, Jodi
Sarkar, Sucharita
Quinn, Caitlin M.
Polenova, Tatyana
ANNUAL REPORTS ON NMR SPECTROSCOPY, VOL 102, 2021, 102 : 81 - 151
[49] Solid-state NMR spectroscopy of paramagnetic metallocenes
Heise, H
Köhler, FH
Xie, XL
JOURNAL OF MAGNETIC RESONANCE, 2001, 150 (02) : 198 - 206
[50] Automated projection spectroscopy in solid-state NMR
Alexander Klein
Suresh K. Vasa
Rasmus Linser
Journal of Biomolecular NMR, 2018, 72 : 163 - 170

← 1 2 3 4 5 →