Characterisation of Germanium Monohalides by Solid-State NMR Spectroscopy and First Principles Quantum Chemical Calculations

被引：4

作者：

Hanson, Margaret A. ^{[1
]}

Schnepf, Andreas ^{[2
]}

Terskikh, Victor V. ^{[3
]}

Huang, Yining ^{[1
]}

Baines, Kim M. ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

[2] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany

[3] Natl Ultrahigh Field NMR Facil Solids, Ottawa, ON K1A 0R6, Canada

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2013年 / 66卷 / 10期

基金：

加拿大自然科学与工程研究理事会; 加拿大创新基金会;

关键词：

METALLOID CLUSTER COMPOUNDS; OXIDE MATERIALS; QUADRUPOLAR; CHLORINE; CHEMISTRY; BROMIDE; GLASSES;

D O I：

10.1071/CH13122

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Germanium(I) monohalides are useful starting materials to synthesise small, well defined germanium nanoclusters. However, due to the amorphous nature of solid GeBr and GeCl, details of their solid-state structures remain largely unknown. We investigate the arrangement within these novel binary materials using Cl-35, Br-79, and Ge-73 solid-state NMR spectroscopy at 21.1 T and first principles quantum chemical calculations in order to suggest a possible model for the structure.

引用

页码：1202 / 1210

页数：9

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