The synthesis and characterization of isobutylantimony compounds

被引：4

作者：

Berry, A ^{[1
]}

机构：

[1] USN, Div Chem, Res Lab, Washington, DC 20375 USA

来源：

POLYHEDRON | 1999年 / 18卷 / 20期

关键词：

organoantimony; synthesis; NMR; IR;

D O I：

10.1016/S0277-5387(99)00165-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Six new isobutyl derivatives of antimony have been synthesized in good yields, including the five-coordinate i-Bu3SbI2 and the three-coordinate i-Bu2SbI, i-Bu2SbBr2, i-BuSbBr2, i-Bu2SbH, and i-BuSbH2. The iodides were made from addition of iodine to i-Bu3Sb and subsequent thermal decomposition of i-Bu3SbI2. The bromides were synthesized by thermal exchange reactions of i-Bu3Sb with SbBr3, and the hydrides from reduction of the bromides with LiAlH4. All compounds have been characterized by elemental analysis, IR, and NMR spectroscopy. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

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页码：2609 / 2615

页数：7

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