Aromatic C-H coupling with hindered arylboronic acids by Pd/Fe dual catalysts

被引：124

作者：

Yamaguchi, Kazuya ^{[1
]}

Kondo, Hiroki ^{[1
]}

Yamaguchi, Junichiro ^{[1
]}

Itami, Kenichiro ^{[1
,2
]}

机构：

[1] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[2] Nagoya Univ, Inst Transformat Biomol WPI ITbM, Chikusa Ku, Nagoya, Aichi 4648602, Japan

来源：

CHEMICAL SCIENCE | 2013年 / 4卷 / 09期

关键词：

SUZUKI-MIYAURA REACTION; OXIDATIVE HECK REACTION; ARYL BORONIC ACIDS; DIRECT ARYLATION; BOND ACTIVATION; ENANTIOSELECTIVE SYNTHESIS; ASYMMETRIC-SYNTHESIS; PALLADIUM CATALYSIS; EFFICIENT SYNTHESIS; ROOM-TEMPERATURE;

D O I：

10.1039/c3sc51206a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An aerobic oxidative coupling of arenes/alkenes with arylboronic acids (C-H/C-B coupling) using catalytic Pd(II)-sulfoxide-oxazoline (sox) ligand and iron-phthalocyanine (FePc) has been developed. This dual catalyst system enables the synthesis of sterically hindered heterobiaryls and styrene derivatives under air without stoichiometric co-oxidants. Additionally, this chemistry demonstrated an advance toward an enantioselective biaryl coupling through C-H functionalization.

引用

页码：3753 / 3757

页数：5

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