Stepwise Cosensitization of Nanocrystalline TiO2 Films Utilizing Al2O3 Layers in Dye-Sensitized Solar Cells

被引:139
作者
Choi, Hyunbong [1 ]
Kim, Sanghoon [1 ]
Kang, Sang Ook [1 ]
Ko, Jaejung [1 ]
Kang, Moon-Sung [5 ]
Clifford, John N. [3 ]
Forneli, Amparo [3 ]
Palomares, Emilio [2 ,3 ]
Nazeeruddin, Mohammad K. [4 ]
Graetzel, Michael [4 ]
机构
[1] Korea Univ, Dept New Mat Chem, Jochiwon 339700, Chungnam, South Korea
[2] ICREA, Barcelona 08010, Spain
[3] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain
[4] Ecole Polytech Fed Lausanne, Fac Sci Base, Inst Sci & Ingn Chim, LPI, CH-1015 Lausanne, Switzerland
[5] Samsung Adv Inst Technol SAIT, Energy & Environm Lab, Yongin 446712, South Korea
关键词
aluminum oxide; electron transfer; hole transfer; sensitizers; titanium dioxide;
D O I
10.1002/anie.200802852
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Doubly sensitized: Stepwise cosensitization is carried out on Al2O3-coated nanocrystalline TiO2 layers using two organic dyes (JK-2 and SQ1) having complementary spectral absorption bands in the visible region. The Al2O3 coating results in the retardation of the interfacial charge recombination dynamics at the oxide/sensitizer interface and improves the overall performance of the dye-sensitized solar cells. CB = conduction band. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:8259 / 8263
页数:5
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