Synthesis and characterization of platinum and palladium pyrrolidinedithiocarbamate complexes

被引：7
|
作者：
Almazahreh, Laith [1 ]
El-khateeb, Mohammad [2 ]
Harb, Mohammad [3 ]
Goerls, Helmar [1 ]
Weigand, Wolfgang [1 ]
机构：
[1] Univ Jena, Inst Anorgan & Analyt Chem, D-07743 Jena, Germany
[2] Jordan Univ Sci & Technol, Dept Chem, Irbid 22110, Jordan
[3] Umm Al Qura Univ, Dept Chem, Fac Sci Qunfudah, Qunfudah, Saudi Arabia
来源：
TRANSITION METAL CHEMISTRY | 2013年 / 38卷 / 04期
关键词：
RAY CRYSTAL-STRUCTURES; MOLECULAR-STRUCTURE; PHOSPHINE ADDUCTS; METAL-COMPLEXES; SULFUR LIGANDS; IN-VITRO; SALTS; DIETHYLDITHIOCARBAMATE; DITHIOCARBONATE; DITHIOPHOSPHATE;
D O I：
10.1007/s11243-013-9701-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of (PPh3)(2)MCl2 (M = Pd or Pt) with ammonium pyrrolidinedithiocarbamate (NH4S2CNC4H8) in a 1:1 molar ratio gave (PPh3)M(Cl)(kappa (2) S,S-S2CNC4H8) [M = Pt (1), Pd (2)]. On the other hand, the interaction of these compounds in a 1:2 [M:L] molar ratio gave (PPh3)Pt(kappa S-S2CNC4H8)(kappa (2) S,S-S2CNC4H8) (3), which contains both terminal and chelated dithiocarbamato ligands, or a yellow insoluble solid for M = Pd. The bis(diphenylphosphino)ethane platinum or palladium dichlorides [(dppe)MCl2] reacted with the same ligand to give the salts [(dppe)M(kappa (2) S,S-S2CNC4H8)]Cl (M = Pt (4), Pd (5) which have only one chelating dithiocarbamato ligand. The new compounds were characterized by H-1-, C-13{H-1}- and P-31-n.m.r. spectroscopy, mass spectrometry, elemental analysis and X-ray single crystal structure analysis.
引用
收藏
页码：377 / 383
页数：7
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