An Integrated Approach for the Production and Isolation of 5-Hydroxymethylfurfural from Carbohydrates

被引：82
作者：
Simeonov, Svilen P. [1 ,2 ,3 ,4 ]
Coelho, Jaime A. S. [1 ,2 ,3 ]
Afonso, Carlos A. M. [1 ,2 ,3 ]
机构：
[1] Univ Lisbon, Fac Farm, Res Inst Med & Pharmaceut Sci, P-1049001 Lisbon, Portugal
[2] CQFM, P-1049001 Lisbon, Portugal
[3] Inst Super Tecn, IN Inst Nanosci & Nanotechnol, P-1049001 Lisbon, Portugal
[4] Bulgarian Acad Sci, Ctr Phytochem, Inst Organ Chem, BU-1113 Sofia, Bulgaria
来源：
CHEMSUSCHEM | 2012年 / 5卷 / 08期
关键词：
carbohydrates; halides; heterogeneous catalysis; industrial chemistry; renewable resources; IONIC LIQUIDS; CONVERSION; FRUCTOSE; BIOMASS; FUELS; CHEMICALS; TRANSFORMATION; CATALYSTS; SOLVENTS; GLUCOSE;
D O I：
10.1002/cssc.201200236
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Crystal clear: An integrated, simple, efficient, reusable, and scalable methodology for the dehydration of fructose to HMF offers outstanding yields and high purities. The method uses wet tetraethylammonium bromide as reaction medium, allowing the isolation of HMF by crystallization from the reaction medium. The process is also feasible starting from other carbohydrates, such as glucose, sucrose, or inulin. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：1388 / 1391
页数：4
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