Terahertz spectroscopic study on order-disorder phase transition of nonadecane

被引：7

作者：

Tanno, Takenori ^{[1
]}

Asari, Junya ^{[2
]}

Yodokawa, Shinichi ^{[2
]}

Kurabayashi, Toru ^{[2
]}

机构：

[1] Akita Univ, Venture Incubat Ctr, Akita 0108502, Japan

[2] Akita Univ, Fac Engn & Resource Sci, Akita 0108502, Japan

来源：

CHEMICAL PHYSICS | 2015年 / 461卷

关键词：

Terahertz spectroscopy; Nonadecane; Paraffin; Order-disorder transition; Rotator phase; CRYSTAL VIBRATIONS; WAVE GENERATION; FREQUENCY; PARAFFINS; PURE;

D O I：

10.1016/j.chemphys.2015.08.022

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Terahertz transmission spectra of nonadecane (C19H40) in the crystalline and rotator phases were measured over the frequency range of 1-5.5 THz. The absorption peak at 2.2 THz, related to intermolecular interaction, was observed only in the crystalline phase. Using the absorbance at this frequency, the transition between the two phases was investigated. A model of the orientational order-disorder transition of the molecule is presented to qualitatively explain the transition rate. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：25 / 28

页数：4

共 19 条

[1] LATTICE-FREQUENCY STUDIES OF CRYSTALLINE AND FOLD STRUCTURE IN POLYETHYLENE
BANK, MI
KRIMM, S
[J]. JOURNAL OF APPLIED PHYSICS, 1968, 39 (11) : 4951 - &
[2] X-RAY STUDY OF THE ROTATOR PHASE OF THE ODD-NUMBERED PARAFFINS C17H36, C19H40, AND C21H44
DOUCET, J
DENICOLO, I
CRAIEVICH, A
[J]. JOURNAL OF CHEMICAL PHYSICS, 1981, 75 (03) : 1523 - 1529
[3] ASSIGNMENT OF 71-CM-1 BAND IN POLYETHYLENE
KRIMM, S
BANK, MI
[J]. JOURNAL OF CHEMICAL PHYSICS, 1965, 42 (11) : 4059 - &
[4] ARRANGEMENT OF ROTATING MOLECULES IN HIGH-TEMPERATURE FORM OF NORMAL PARAFFINS
LARSSON, K
[J]. NATURE, 1967, 213 (5074) : 383 - &
[5] The crystal structure of the normal paraffins at temperatures ranging from that of liquid air to the melting points
Muller, A
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-CONTAINING PAPERS OF A MATHEMATICAL AND PHYSICAL CHARACTER, 1930, 127 (805) : 417 - U14
[6] Terahertz disorder-localized rotational modes and lattice vibrational modes in the orientationally-disordered and ordered phases of camphor
Nickel, Daniel V.
Ruggiero, Michael T.
Korter, Timothy M.
Mittleman, Daniel M.
[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (10) : 6734 - 6740
[7] A comparative study of THz spectra
Nishizawa, J
Suto, K
Sasaki, T
Tanno, T
[J]. PROCEEDINGS OF THE JAPAN ACADEMY SERIES B-PHYSICAL AND BIOLOGICAL SCIENCES, 2005, 81 (01): : 20 - 25
[8] Parrott E.P.J., 2012, TERAHERTZ SPECTROSCO, P191
[9] Dynamics of molecules and phase transitions in the crystals of pure and binary mixtures of n-paraffins
Puchkovska, GO
Makarenko, SP
Danchuk, VD
Kravchuk, AP
Baran, J
Kotelnikova, EN
Filatov, SK
[J]. JOURNAL OF MOLECULAR STRUCTURE, 2002, 614 (1-3) : 159 - 166
[10] Rao C.N. R., 1997, New directions in solid state chemistry, V2nd

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