Intramolecular Diels-Alder route to angularly oxygenated hydrindanes. Synthesis of the functionalized bicylic skeleton present in galiellalactone

被引：4

作者：

Hossain, Md Firoj ^{[1
]}

Yadav, Ram Naresh ^{[1
]}

Mondal, Sujit ^{[1
]}

Jana, Anupam ^{[1
]}

Ghosh, Subrata ^{[1
]}

机构：

[1] Indian Assoc Cultivat Sci, Dept Organ Chem, Kolkata 700032, India

来源：

TETRAHEDRON | 2013年 / 69卷 / 37期

关键词：

Carbohydrate; Diels-Alder reaction; Hydrindanes; Metathesis; OLEFIN METATHESIS; ALDOL; DIENE; HETEROCYCLES; OXIDATION;

D O I：

10.1016/j.tet.2013.07.014

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Intramolecular Diels-Alder reaction of trienones embedded in a sugar derivative with or without Me substituents on the diene part has been investigated for synthesis of hydrindanes with angular oxygen functionality. One of these adducts has been transformed to a functionalized bicyclic skeleton present in galiellalactone. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：7956 / 7963

页数：8

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