Enhanced Thermal Conductivity of EpoxyGraphene Composites by Using Non-Oxidized Graphene Flakes with Non-Covalent Functionalization

被引:605
作者
Song, Sung Ho [1 ]
Park, Kwang Hyun [1 ]
Kim, Bo Hyun [1 ]
Choi, Yong Won [1 ]
Jun, Gwang Hoon [1 ]
Lee, Dong Ju [1 ]
Kong, Byung-Seon [2 ]
Paik, Kyung-Wook [1 ]
Jeon, Seokwoo [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Taejon 305701, South Korea
[2] KCC Cent Res Inst, Gyeonggi Do 446912, South Korea
基金
新加坡国家研究基金会;
关键词
graphene flakes; non-covalent functionalization; dispersion; nanocomposites; WALLED CARBON NANOTUBES; GRAPHITE-NANOPLATELET; HEAT-FLOW; SOLVENT; DISPERSIONS; EXFOLIATION; NANOCOMPOSITES; SOLUBILITY; RESISTANCE; TRANSPORT;
D O I
10.1002/adma.201202736
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Homogeneous distribution of graphene flakes in a polymer matrix, still preserving intrinsic material properties, is key to successful composite applications. A novel approach is presented to disperse non-oxidized graphene flakes with non-covalent functionalization of 1-pyrenebutyric acid and to fabricate nanocomposites with outstanding thermal conductivity (∼1.53 W/mK) and mechanical properties (∼1.03 GPa). © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:732 / 737
页数:6
相关论文
共 48 条
[1]   Chip scale thermal management of high brightness LED packages [J].
Arik, M ;
Weaver, S .
FOURTH INTERNATIONAL CONFERENCE ON SOLID STATE LIGHTING, 2004, 5530 :214-223
[2]   Organic solvent dispersions of single-walled carbon nanotubes: Toward solutions of pristine nanotubes [J].
Ausman, KD ;
Piner, R ;
Lourie, O ;
Ruoff, RS ;
Korobov, M .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (38) :8911-8915
[3]   Superior thermal conductivity of single-layer graphene [J].
Balandin, Alexander A. ;
Ghosh, Suchismita ;
Bao, Wenzhong ;
Calizo, Irene ;
Teweldebrhan, Desalegne ;
Miao, Feng ;
Lau, Chun Ning .
NANO LETTERS, 2008, 8 (03) :902-907
[4]  
Balandin AA, 2011, NAT MATER, V10, P569, DOI [10.1038/nmat3064, 10.1038/NMAT3064]
[5]   Carbon nanotube composites for thermal management [J].
Biercuk, MJ ;
Llaguno, MC ;
Radosavljevic, M ;
Hyun, JK ;
Johnson, AT ;
Fischer, JE .
APPLIED PHYSICS LETTERS, 2002, 80 (15) :2767-2769
[6]   Noncovalent sidewall functionalization of single-walled carbon nanotubes for protein immobilization [J].
Chen, RJ ;
Zhang, YG ;
Wang, DW ;
Dai, HJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (16) :3838-3839
[7]   Stable dispersions of graphene and highly conducting graphene films: a new approach to creating colloids of graphene monolayers [J].
Chen, Yao ;
Zhang, Xiong ;
Yu, Peng ;
Ma, Yanwei .
CHEMICAL COMMUNICATIONS, 2009, (30) :4527-4529
[8]   Improving thermal conductivity while retaining high electrical resistivity of epoxy composites by incorporating silica-coated multi-walled carbon nanotubes [J].
Cui, Wei ;
Du, Feipeng ;
Zhao, Jinchao ;
Zhang, Wei ;
Yang, Yingkui ;
Xie, Xiaolin ;
Mai, Yiu-Wing .
CARBON, 2011, 49 (02) :495-500
[9]   Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material [J].
Eda, Goki ;
Fanchini, Giovanni ;
Chhowalla, Manish .
NATURE NANOTECHNOLOGY, 2008, 3 (05) :270-274
[10]   Improved thermal conductivity for chemically functionalized exfoliated graphite/epoxy composites [J].
Ganguli, Sabyasachi ;
Roy, Ajit K. ;
Anderson, David P. .
CARBON, 2008, 46 (05) :806-817