Nucleophilic Addition of Polyfunctional Amines to Acetonitrile Derivatives of closo-Borate Anions [BnHn-1NCCH3]- (n=10, 12)

被引：11

作者：

Nelyubin, A., V ^{[1
]}

Sokolov, M. S. ^{[2
]}

Selivanov, N. A. ^{[1
]}

Bykov, A. Yu ^{[1
]}

Klyukin, I. N. ^{[1
]}

Zhdanov, A. P. ^{[1
]}

Zhizhin, K. Yu ^{[1
]}

Kuznetsov, N. T. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

[2] MIREA Russian Technol Univ, Moscow 119571, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2022年 / 67卷 / 11期

基金：

俄罗斯科学基金会;

关键词：

closo-dodecaborate anion; closo-decaborate anion; nitrile derivatives; nucleophilic addition; biologically active amines; NITRILIUM DERIVATIVES; DECABORATE; NITROGEN; METHANE; SALTS;

D O I：

10.1134/S003602362260109X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Methods for the preparation of new amidine-closo-borates based on the processes of nucleophilic addition of bifunctional amines containing free functional groups -NH2, -SH to nitrile derivatives of the closo-decaborate and closo-dodecaborate anions have been developed. These derivatives can potentially act as agents for B-10-NCT and serve as starting compounds for further preparation of borylated derivatives by organic chemistry methods. The structures of the obtained compounds have been confirmed by H-1, B-11, C-13 NMR spectroscopies and ESI mass spectroscopy.

引用

页码：1751 / 1755

页数：5

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