Preparation of new type of organocatalysts having a carbohydrate scaffold

被引：19

作者：

Agoston, Karoly ^{[1
]}

Fuegedi, Peter ^{[1
]}

机构：

[1] Hungarian Acad Sci, Inst Organ Chem, Res Ctr Nat Sci, H-1025 Budapest, Hungary

来源：

CARBOHYDRATE RESEARCH | 2014年 / 389卷

关键词：

Bifunctional organocatalysts; Thiourea-amine type catalysts; Carbohydrate scaffold; Michael addition; ENANTIOSELECTIVE MICHAEL ADDITION; AZA-HENRY REACTION; BIFUNCTIONAL THIOUREA; 1,3-DICARBONYL COMPOUNDS; NITROOLEFINS; DERIVATIVES; CONVERSION; KETONES;

D O I：

10.1016/j.carres.2013.12.026

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The synthesis of nine new, bifunctional organocatalysts having carbohydrate scaffolds has been accomplished. In these catalysts both of the catalytic amino and thiourea functions are directly attached to a carbohydrate core. The activities of the newly prepared catalysts were tested in a Michael addition. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：50 / 56

页数：7