Hydrogenation of Arenes by Dual Activation: Reduction of Substrates Ranging from Benzene to C60 Fullerene under Ambient Conditions

被引：73
作者：
Deshmukh, Ravindra R. [1 ]
Lee, Ji Woong [1 ]
Shin, Ueon Sang [1 ]
Lee, Jin Yong [1 ]
Song, Choong Eui [1 ]
机构：
[1] Sungkyunkwan Univ, Dept Chem, Suwon 440746, Gyeonggi, South Korea
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 45期
关键词：
fullerenes; hydrogenation; ionic liquids; Lewis acids; palladium;
D O I：
10.1002/anie.200803850
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Tackling aromaticity: The title reaction was accomplished by simultaneous activation of molecular hydrogen and the aromatic substrate by Pd/C and a Lewis acidic ionic liquid, respectively. Even benzene and C60 fullerene were hydrogenated under ambient conditions (1 bar of H2 at room temperature). An ionic hydrogenation mechanism (see scheme) is supported by characterization of a stabilized arenium intermediate. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：8615 / 8617
页数：3
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