Enthalpies of mixing and state of components in aqueous-organic mixtures with nets of hydrogen bonds

被引：13
作者：
Batov, DV [1 ]
Zaichikov, AM
Slyusar, VP
Korolev, VP
机构：
[1] Russian Acad Sci, Inst Solut Chem, Ivanovo, Russia
[2] Ivanovo State Univ Chem Engn, Ivanovo, Russia
[3] Ivanovo State Med Acad, Ivanovo, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2001年 / 71卷 / 08期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1023/A:1013256524865
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The enthalpies of mixing of water with glycerol over the entire composition range were determined at 298.15 K. The partial excess enthalpies of the components of mixtures of water with glycerol, ethylene glycol, 1,2- and 1,3-propylene glycol, and formamide were estimated and used for examining solvation and the state of water and the organic components in the solutions. The composition of the solvation shells of the components of the mixtures were shown to depend on the nature and structure of the organic solvent.
引用
收藏
页码：1208 / 1214
页数：7
相关论文
共 32 条
[11]  
EMELIN VP, 1972, ZH STRUKT KHIM, V13, P147
[12]   Conformation and Hydration of Sugars and Related Compounds in Dilute Aqueous Solution [J].
Franks, F. ;
Reid, D. S. ;
Suggett, A. .
JOURNAL OF SOLUTION CHEMISTRY, 1973, 2 (2-3) :99-113
[13]   TEST MEASUREMENTS AND ANALYSIS OF ERRORS FOR A NEW EQUIPMENT FOR THE DETERMINATION OF EXCESS-HEAT DATA [J].
HUEMER, H ;
PLATZER, E ;
REHAK, K .
THERMOCHIMICA ACTA, 1991, 187 :95-112
[14]  
Klimova V. A., 1967, OSNOVNYE MIKROMETODY
[15]  
KOROLEV VP, 1986, IZV VUZ KHIM KH TEKH, V29, P116
[16]  
KUDRYAVTSEV AB, 1974, ZH STRUKT KHIM, V15, P136
[17]  
KUMEEV RS, 1992, ZH OBSHCH KHIM+, V62, P1248
[18]  
LEBEDEV YA, 1981, TERMOKHIMIYA PAROOBR
[19]  
MANOHARAMURTHY N, 1978, INDIAN J CHEM A, V16, P558
[20]   MOLAR EXCESS ENTHALPIES FOR WATER + ETHANEDIOL, + 1,2-PROPANEDIOL, AND + 1,3-PROPANEDIOL AT 298.15-K [J].
MATSUMOTO, Y ;
TOUHARA, H ;
NAKANISHI, K ;
WATANABE, N .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1977, 9 (08) :801-805
1234