Synthesis of crystalline yttrium oxycarbonate in a single phase

被引：23

作者：

Imanaka, N ^{[1
]}

Masui, T ^{[1
]}

Mayama, Y ^{[1
]}

Koyabu, K ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn & Handai Frontier Res Ctr, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2005年 / 178卷 / 11期

关键词：

crystalline Y2O2CO3; flux method; FT-IR;

D O I：

10.1016/j.jssc.2005.09.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystalline yttrium oxycarbonate, Y2O2CO3, Was synthesized by our original flux method using the 0.476Li(2)CO(3)-0.270Na(2) CO3-0.254K(2)CO(3) eutectic mixture at 450 degrees C. The oxycarbonate was characterized by X-ray powder diffraction (XRD), thermogravimetric analysis (TGA), and Fourier-transfer infrared spectroscopy (FT-IR). The Y2O2CO3 prepared by the flux method was a crystalline single phase of hexagonal rare earth oxycarbonate (type-It). This is the first report on the single-phase synthesis of crystalline hexagonal type-II Y2O2CO3. (c) 2005 Elsevier Inc. All rights reserved.

引用

页码：3601 / 3603

页数：3

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