(μ-diphenylphosphanido-κ2P:P′)bis[2,2′(pyridine-2,6-diyl)diphenyl-κ3C1,N,C1′gold(III)] perchlorate acetonitrile solvate

被引：3

作者：

Li, Xin-Sheng ^{[1
]}

Mo, Juan ^{[1
]}

Zhang, Su-Mei ^{[1
]}

Yuan, Li ^{[1
]}

Liu, Jian-Hua ^{[1
]}

机构：

[1] Henan Agr Univ, Coll Anim Husb & Vet Studies, Zhengzhou 450002, Henan Province, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷

关键词：

D O I：

10.1107/S1600536808024537

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title complex, [Au-2(C17H11N)(2)(C12H10P)]ClO4 center dot C2H3N, contains two Au-III atoms bridged by a diphenylphosphanide ligand. Each Au atom is in a square-planar environment coordinated by diphenylphosphanide and 2,6-diphenylpyridine ligands. There are weak pi-pi stacking interactions between neighbouring molecules (the interplanar separations between two neighbouring dpp units are 3.40 and 3.57 angstrom). The intramolecular Au center dot center dot center dot Au separation is 3.788(5)angstrom. The crystal structure shows weak intermolecular C-H center dot center dot center dot O and CH center dot center dot center dot N hydrogen bonds involving an O atom of the perchlorate counter-ion and the N atom of the acetonitrile solvent molecule, respectively.

引用

页码：M1126 / U261

页数：17

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