Preparation of magnetic Fe3O4 particles modified sawdust as the adsorbent to remove strontium ions

被引:117
作者
Cheng, Zihong [1 ]
Gao, Zhanxian [1 ]
Ma, Wei [1 ]
Sun, Qi [2 ]
Wang, Baodong [2 ]
Wang, Xiaoguang [2 ]
机构
[1] Dalian Univ Technol, Dept Chem, Dalian 116023, Peoples R China
[2] Natl Inst Clean & Low Carbon Energy, Beijing 102209, Peoples R China
关键词
Sawdust; Magnetic Fe3O4 particles; Chitosan; Strontium ions; Adsorption; AQUEOUS-SOLUTION; ADSORPTION; SORPTION; BIOSORPTION; NANOPARTICLES; SEPARATION; ISOTHERMS; BIOSORBENT; ALUMINUM; KINETICS;
D O I
10.1016/j.cej.2012.07.078
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Magnetic Fe3O4 particles modified sawdust (MCS) was prepared by using chitosan as the bridging reagent and characterized by FTIR analysis, and the results indicated that sawdust was successfully modified by magnetic Fe3O4 particles by connection of chitosan. The results obtained from the strontium ions adsorption experiments showed that the MCS was an effective material to remove strontium ions from aqueous solutions. And most importantly, the adsorption process was safely and easily controlled, the separation of MCS from solutions after adsorption was fast because of the magnetic modification. The adsorption of strontium ions by MCS was affected by pH, background electrolyte, adsorbent dosage and contact time. The adsorption process could achieve equilibrium in 30 min, and the maximum adsorption capacity studied at different initial concentrations was 12.59 mg/g. The adsorption process was a physical process which could be approved by the adsorption free energy and well fitted by the pseudo first order model. (C) 2012 Published by Elsevier B.V.
引用
收藏
页码:451 / 457
页数:7
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