New pentafluoro-λ6-sulfanyl (SF5) perfluoroalkyl benzene derivatives

被引：9

作者：

Hodges, AM ^{[1
]}

Winter, RW ^{[1
]}

Winner, SW ^{[1
]}

Preston, DA ^{[1
]}

Gard, GL ^{[1
]}

机构：

[1] Portland State Univ, Dept Chem, Portland, OR 97207 USA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2002年 / 114卷 / 01期

基金：

美国国家科学基金会;

关键词：

pentafluorothiofluoroalkyl benzene derivatives; IR and NMR spectroscopy; HRMS and MS;

D O I：

10.1016/S0022-1139(01)00499-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Preparation of the following new SF5-perfluoroalkyl benzene derivatives, m-SF5CF2CF2C6H4X (X = NO2, NH2, OH, I, NHCOCH3, SO2Cl, SO3H, SO3K) has been achieved. The new compounds were characterized by their respective IR, NMR and HRMS or elemental analysis. (C) 2002 Published by Elsevier Science B.V.

引用

页码：3 / 8

页数：6

共 8 条

[1] A new method for the synthesis of aromatic sulfurpentafluorides and studies of the stability of the sulfurpentafluoride group in common synthetic transformations [J].

Bowden, RD ;

Comina, PJ ;

Greenhall, MP ;

Kariuki, BM ;

Loveday, A ;

Philp, D .

TETRAHEDRON, 2000, 56 (21) :3399-3408

[2]

BROWN JK, 1965, ADV FLUORINE CHEM, V4, P258

[3] THE INFRA-RED SPECTRA OF SOME DERIVATIVES OF SULPHUR HEXAFLUORIDE [J].

CROSS, LH ;

CUSHING, G ;

ROBERTS, HL .

SPECTROCHIMICA ACTA, 1961, 17 (03) :344-351

[4]

HODGES AM, 2001, IN PRESS J FLUORINE

[5]

HUTCHINSON J, 1973, J FLUORINE CHEM, V3, P429

[6] New fluoroalkenes and alcohol with pentafluoro-λ6-sulfanyl (SF5) terminal groupings [J].

Nixon, PG ;

Renn, J ;

Terjeson, RJ ;

Choi, YS ;

Winter, R ;

Gard, GL .

JOURNAL OF FLUORINE CHEMISTRY, 1998, 91 (01) :13-18

[7] ARYLSULFUR PENTAFLUORIDES [J].

SHEPPARD, WA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (16) :3064-&

[8] Pentafluoro-lambda(6)-sulfanyl (SF5) fluoroalkyl iodides [J].

Terjeson, RJ ;

Renn, J ;

Winter, R ;

Gard, GL .

JOURNAL OF FLUORINE CHEMISTRY, 1997, 82 (01) :73-78

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