Uniform Metal (Hydr)Oxide Particles from Water/Ionic Liquid Precursor (ILP) Mixtures

被引：35
|
作者：
Li, Zhonghao [1 ]
Rabu, Pierre [2 ]
Strauch, Peter [1 ]
Mantion, Alexandre [3 ]
Taubert, Andreas [1 ,4 ]
机构：
[1] Univ Potsdam, Inst Chem, D-14476 Golm, Germany
[2] Univ Strasbourg, CNRS, UMR7504, Inst Phys & Chim Mat Strasbourg, F-67034 Strasbourg, France
[3] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland
[4] Max Planck Inst Colloids & Interfaces, D-14476 Golm, Germany
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2008年 / 14卷 / 27期
基金：
瑞士国家科学基金会;
关键词：
ionic liquids; magnetic properties; nanostructures; oxides; synthesis design;
D O I：
10.1002/chem.200800106
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We have recently shown that the hydrated ionic liquid tetrabutylammonium hydroxide (TBAH) is an efficient ionic liquid precursor (ILP) for the fabrication of ZnO/carbohydrate materials (D. Mumalo-Djokic, W. B. Stern, A. Taubert, Cryst. Growth Des. 2008, 8, 330). The current paper shows that ZnO is just one example out of the large group of technologically important metal (hydr)oxides that can be made using TBAH. Simply by using different metal acetates as precursors in TBAH, it is possible to make a wide variety of metal (hydr)oxides with well-defined size, morphology, and chemical composition. It is also possible to dope metal oxide particles or to synthesize mixed metal oxide particles, and therefore to control properties like magnetism.
引用
收藏
页码：8409 / 8417
页数：9
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