Platinum-group minerals from the Jinbaoshan Pd-Pt deposit, SW China: evidence for magmatic origin and hydrothermal alteration

被引:40
|
作者
Wang, Christina Yan [1 ,2 ]
Prichard, Hazel M. [3 ]
Zhou, Mei-Fu [2 ]
Fisher, Peter C. [3 ]
机构
[1] Chinese Acad Sci, Guangzhou Inst Geochem, Guangzhou 510640, Guangdong, Peoples R China
[2] Univ Hong Kong, Dept Earth Sci, Hong Kong, Hong Kong, Peoples R China
[3] Cardiff Univ, Sch Earth & Ocean Sci, Cardiff, S Glam, Wales
关键词
platinum-group minerals; hydrothermal alteration; Pt-Pd ores; Jinbaoshan; Emeishan Large Igneous Province; China;
D O I
10.1007/s00126-008-0196-0
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
The Jinbaoshan Pt-Pd deposit in Yunnan, SW China, is hosted in a wehrlite body, which is a member of the Permian (similar to 260 Ma) Emeishan Large Igneous Province (ELIP). The deposit is reported to contain one million tonnes of Pt-Pd ore grading 0.21% Ni and 0.16% Cu with 3.0 g/t (Pd + Pt). Platinum-group minerals (PGM) mostly are similar to 10 mu m in diameter, and are commonly Te-, Sn- and As-bearing, including moncheite (PtTe(2)), atokite (Pd(3)Sn), kotulskite (PdTe), sperrylite (PtAs(2)), irarsite (IrAsS), cooperite (PtS), sudburyite (PdSb), and Pt-Fe alloy. Primary rock-forming minerals are olivine and clinopyroxene, with clinopyroxene forming anhedral poikilitic crystals surrounding olivine. Primary chromite occurs either as euhedral grains enclosed within olivine or as an interstitial phase to the olivine. However, the intrusion has undergone extensive hydrothermal alteration. Most olivine grains have been altered to serpentine, and interstitial clinopyroxene is often altered to actinolite/tremolite and locally biotite. Interstitial chromite grains are either partially or totally replaced by secondary magnetite. Base-metal sulfides (BMS), such as pentlandite and chalcopyrite, are usually interstitial to the altered olivine. PGM are located with the BMS and are therefore also interstitial to the serpentinized olivine grains, occurring within altered interstitial clinopyroxene and chromite, or along the edges of these minerals, which predominantly altered to actinolite/tremolite, serpentine and magnetite. Hydrothermal fluids were responsible for the release of the platinum-group elements (PGE) from the BMS to precipitate the PGM at low temperature during pervasive alteration. A sequence of alteration of the PGM has been recognized. Initially moncheite and atokite have been corroded and recrystallized during the formation of actinolite/tremolite, and then, cooperite and moncheite were altered to Pt-Fe alloy where they are in contact with serpentine. Sudburyite occurs in veins indicating late Pd mobility. However, textural evidence shows that the PGM are still in close proximity to the BMS. They occur in PGE-rich layers located at specific igneous horizons in the intrusion, suggesting that PGE were originally magmatic concentrations that, within a PGE-rich horizon, crystallized with BMS late in the olivine/clinopyroxene crystallization sequence and have not been significantly transported during serpentinization and alteration.
引用
收藏
页码:791 / 803
页数:13
相关论文
共 33 条
  • [31] Origin of fluorite mineralisation and hydrothermal alteration at the Chandidongri deposit, Rajnandgaon District, Central India - Evidence from oxygen and hydrogen isotopes
    Changkakoti, A.
    Pandalai, H. S.
    Gray, J.
    Ahmad, S.
    Perasud, E. R.
    JOURNAL OF THE GEOLOGICAL SOCIETY OF INDIA, 2006, 67 (01) : 33 - 40
  • [32] Segregation of magmatic fluids and their potential in the mobilization of platinum-group elements in the South Kawishiwi Intrusion, Duluth Complex, Minnesota - Evidence from petrography, apatite geochemistry and coexisting fluid and melt inclusions
    Gal, Benedek
    Molnar, Ferenc
    Guzmics, Tibor
    Mogessie, Aberra
    Szabo, Csaba
    Peterson, Dean M.
    ORE GEOLOGY REVIEWS, 2013, 54 : 59 - 80
  • [33] Multiple magma evolution and ore-forming processes of the Hongge layered intrusion, SW China: Insights from Sr-Nd isotopes, trace elements and platinum-group elements
    Liao, Mingyang
    Tao, Yan
    Song, Xieyan
    Li, Yubang
    Xiong, Feng
    JOURNAL OF ASIAN EARTH SCIENCES, 2015, 113 : 1082 - 1099