Catalytic asymmetric β-peroxidation of nitroalkenes

被引：46
作者：
Russo, Alessio [1 ]
Lattanzi, Alessandra [1 ]
机构：
[1] Univ Salerno, Dipartimento Chim, I-84084 Fisciano, Italy
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2008年 / 350卷 / 13期
关键词：
asymmetric catalysis; Michael addition; nitroalkenes; organocatalysis; peroxides;
D O I：
10.1002/adsc.200800387
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The first example of an asymmetric P-peroxidation of nitroalkenes is disclosed. The reaction is promoted by catalytic loadings of a commercially available diaryl-2-pyrrolidinemethanol derivative and tert-butyl hydroperoxide as the oxidant. A synthetically useful class of peroxides is obtained in good yield and enantioselectivity (up to 84% ee).
引用
收藏
页码：1991 / 1995
页数：5
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