Catalytic asymmetric β-peroxidation of nitroalkenes

被引：46

作者：

Russo, Alessio ^{[1
]}

Lattanzi, Alessandra ^{[1
]}

机构：

[1] Univ Salerno, Dipartimento Chim, I-84084 Fisciano, Italy

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2008年 / 350卷 / 13期

关键词：

asymmetric catalysis; Michael addition; nitroalkenes; organocatalysis; peroxides;

D O I：

10.1002/adsc.200800387

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The first example of an asymmetric P-peroxidation of nitroalkenes is disclosed. The reaction is promoted by catalytic loadings of a commercially available diaryl-2-pyrrolidinemethanol derivative and tert-butyl hydroperoxide as the oxidant. A synthetically useful class of peroxides is obtained in good yield and enantioselectivity (up to 84% ee).

引用

页码：1991 / 1995

页数：5

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