The Oxidation of Toluene on Transition Metal Oxides

被引:11
|
作者
Tomskii, I. S. [1 ]
Vishnetskaya, M. V. [1 ]
Rufov, Yu. N. [2 ]
机构
[1] Gubkin State Univ Oil & Gas, Moscow 117917, Russia
[2] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow, Russia
关键词
CATALYTIC-OXIDATION; V2O5/TIO2; CATALYSTS; VANADIUM; BENZENE;
D O I
10.1134/S0036024409110107
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The oxidation of toluene on pure vanadium and molybdenum oxides was found to follow independent paths; it was benzene ring oxidation on V2O5 and side chain oxidation on MoO3. On mixed xV(2)O(5) center dot yMoO(3) oxides, the main reaction was the addition at the double bond preferably positioned meta rather than one-electron oxidation.
引用
收藏
页码:1868 / 1872
页数:5
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