Control of bacterial extracellular electron transfer by a solid-state mediator of polyaniline nanowire arrays

被引:64
作者
Ding, Chunmei [1 ]
Liu, Huan [1 ]
Zhu, Ying [1 ]
Wan, Meixiang [2 ]
Jiang, Lei [1 ,2 ]
机构
[1] BeiHang Univ, Key Lab Bioinspired Smart Interfacial Sci & Techn, Minist Educ, Sch Chem & Environm, Beijing 100191, Peoples R China
[2] Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China
基金
中国国家自然科学基金; 北京市自然科学基金;
关键词
SHEWANELLA-ONEIDENSIS MR-1; ELECTRICITY-GENERATION; DOPED POLYANILINE; IRON; CELL; OXIDATION; ANODE; REDUCTION; COMPOSITE; ELECTROCHEMISTRY;
D O I
10.1039/c2ee22269h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report that polyaniline nanowire arrays (PANI-NAs) can serve as a tunable terminal polymeric mediator for bacterial extracellular electron transfer (EET) by members of the genus Shewanella. Multiple oxidation levels of PANI at different applied potentials lead to multiple abilities in mediating EET, while the aligned nanostructures enable enhanced local topological interactions with microbes and hence efficient electrical interaction. PANI-NA therefore exhibits a unique property that allows for efficient EET reactions to proceed in a controlled manner.
引用
收藏
页码:8517 / 8522
页数:6
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