Sulfated SnO2 As a high-performance catalyst for alkene oligomerization

被引：8
作者：
Yurkova, L. L. [1 ]
Lermontov, S. A. [1 ]
Kazachenko, V. P. [1 ]
Ivanov, V. K. [2 ,3 ]
Lermontov, A. S. [2 ]
Baranchikov, A. E. [2 ]
Vasil'eva, L. P. [4 ]
机构：
[1] Russian Acad Sci, Inst Physiologically Act Cpds, Noginskii Raion 142432, Moscow Oblast, Russia
[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
[3] Moscow MV Lomonosov State Univ, Moscow 119899, Russia
[4] Russian Acad Sci, Inst Problems Chem Phys, Noginskii Raion 142432, Moscow Oblast, Russia
来源：
INORGANIC MATERIALS | 2012年 / 48卷 / 10期
基金：
俄罗斯基础研究基金会;
关键词：
TIN OXIDE; SOLID SUPERACIDS; ACIDITY HIGHER; N-HEPTANE; TEMPERATURE; OXIDATION; EFFICIENT; ESTERIFICATION; ALKYLATION; ACYLATION;
D O I：
10.1134/S0020168512100147
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Nanoparticulate (3-5 nm) sulfated tin dioxide shows high catalytic activity for the oligomerization of isobutylene, hexene-1, and cyclohexene. The acidity (Hammett acidity function H (0)) of sulfated stannia reaches H (0) = -16.04. We have studied the effect of synthesis conditions on the physicochemical and functional properties of sulfated SnO2.
引用
收藏
页码：1012 / 1019
页数：8
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