Sulfated SnO2 As a high-performance catalyst for alkene oligomerization

被引：8

作者：

Yurkova, L. L. ^{[1
]}

Lermontov, S. A. ^{[1
]}

Kazachenko, V. P. ^{[1
]}

Ivanov, V. K. ^{[2
,3
]}

Lermontov, A. S. ^{[2
]}

Baranchikov, A. E. ^{[2
]}

Vasil'eva, L. P. ^{[4
]}

机构：

[1] Russian Acad Sci, Inst Physiologically Act Cpds, Noginskii Raion 142432, Moscow Oblast, Russia

[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

[3] Moscow MV Lomonosov State Univ, Moscow 119899, Russia

[4] Russian Acad Sci, Inst Problems Chem Phys, Noginskii Raion 142432, Moscow Oblast, Russia

来源：

INORGANIC MATERIALS | 2012年 / 48卷 / 10期

基金：

俄罗斯基础研究基金会;

关键词：

TIN OXIDE; SOLID SUPERACIDS; ACIDITY HIGHER; N-HEPTANE; TEMPERATURE; OXIDATION; EFFICIENT; ESTERIFICATION; ALKYLATION; ACYLATION;

D O I：

10.1134/S0020168512100147

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Nanoparticulate (3-5 nm) sulfated tin dioxide shows high catalytic activity for the oligomerization of isobutylene, hexene-1, and cyclohexene. The acidity (Hammett acidity function H (0)) of sulfated stannia reaches H (0) = -16.04. We have studied the effect of synthesis conditions on the physicochemical and functional properties of sulfated SnO2.

引用

页码：1012 / 1019

页数：8

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