Perspective: Understanding of ripening growth model for minimum residual PbI2 and its limitation in the planar perovskite solar cells

被引:52
作者
Kim, Se-Yun [1 ]
Jo, Hyo Jeong [1 ]
Sung, Shi-Joon [1 ]
Kim, Dae-Hwan [1 ]
机构
[1] DGIST, Convergence Res Ctr Solar Energy, Daegu 711873, South Korea
关键词
PERFORMANCE; CRYSTALLIZATION; EFFICIENCY; FILMS;
D O I
10.1063/1.4963841
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The power conversion efficiency of lead halide perovskite solar cells recently surpassed 22.1%. In this study, we suggest the perovskite absorber growth mechanism of the two-step process could be explained by an Ostwald ripening growth model for planar-structure perovskite solar cells. We attempt to find out the source of two main problems such as unreacted PbI2 and non-uniformed morphology by the proposed ripening growth mechanism and experimental results. This growth mechanism opens the way toward understanding a key aspect of the photovoltaic operation of high-efficiency, two-step perovskite solar cells. (C) 2016 Author(s).
引用
收藏
页数:9
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