Photoorganocatalysis. What for?

被引：801

作者：

Ravelli, Davide ^{[1
]}

Fagnoni, Maurizio ^{[1
]}

Albini, Angelo ^{[1
]}

机构：

[1] Univ Pavia, Dept Chem, PhotoGreen Lab, I-27100 Pavia, Italy

来源：

CHEMICAL SOCIETY REVIEWS | 2013年 / 42卷 / 01期

关键词：

PHOTOCHEMICALLY INDUCED ADDITION; VISIBLE-LIGHT PHOTOCATALYSIS; ELECTRON-DEFICIENT ALKENES; GRAPHITIC CARBON NITRIDE; TERTIARY-AMINES; METAL-FREE; PHOTOREDOX CATALYSIS; RADICAL-ADDITION; ALPHA-ENONES; SYNTHETIC APPLICATIONS;

D O I：

10.1039/c2cs35250h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the reactions reviewed, an organic molecule under irradiation catalyzes a chemical reaction. The activation is based either on hydrogen or on electron transfer. Commonly used photoorganocatalysts are aromatic ketones, quinones, heterocycles, dyes; intermediates formed are radicals, radical ions and ions from precursors such as alkanes, alkenes, amines, ethers etc. Oxidation (mainly oxygenation) and reduction processes are obtained along with the alpha-functionalization of amines and ketones, conjugate additions, cycloadditions etc. The key characteristic of the method is the smooth generation of highly reactive intermediates under mild conditions.

引用

页码：97 / 113

页数：17

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