Synthesis, characterization, and crystal structures of two copper(II) complexes derived from 2-bromo-4-chloro-6-[(2-diethylaminoethylimino)methyl]phenol and 2,4-dibromo-6-[(2-isopropylaminoethylimino)methyl]phenol

被引：1

作者：

Miao, Jian-Ying ^{[1
]}

机构：

[1] Baoji Univ Arts & Sci, Dept Chem & Chem Engn, Baoji 721007, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2008年 / 38卷 / 06期

关键词：

synthesis; crystal structure; Schiff base; copper complex;

D O I：

10.1080/15533170802265673

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two mononuclear Schiff base copper(II) complexes, [Cu(L1)(2)] center dot 2NO(3)(1) and [Cu(L2)(2)]center dot 2Br (2) (L1 =2-bromo-4-chloro-6-[(2-diethylaminoethylimino)methyl]phenol, L2 = 2,4-dibromo-6-[(2-isopropylaminoethylimino)methyl]phenol), were synthesized by the reaction of Schiff base ligands with copper salts in methanol solution. The complexes were characterized by elemental analysis, IR spectra, and single crystal X-ray diffraction. The Cu atom in each of the complexes is four-coordinated by two Schiff base ligands, forming a square planar geometry.

引用

页码：545 / 549

页数：5

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