Surface vibrational spectroscopy of sulfuric acid-water mixtures at the liquid-vapor interface

被引：104

作者：

Raduge, C ^{[1
]}

Pflumio, V ^{[1
]}

Shen, YR ^{[1
]}

机构：

[1] UNIV CALIF BERKELEY,LAWRENCE BERKELEY LAB,DIV MAT SCI,DEPT PHYS,BERKELEY,CA 94720

来源：

CHEMICAL PHYSICS LETTERS | 1997年 / 274卷 / 1-3期

关键词：

D O I：

10.1016/S0009-2614(97)00631-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Infrared-visible sum-frequency generation has been used to obtain vibrational spectra of sulfuric acid-water mixtures at the liquid-vapor interface in the OH stretch region. The spectral peaks gradually disappear with increase of sulfuric acid concentration. the dangling OH mode first, followed by the bonded OM modes. Thp results can be understood if the Liquid surfaces are assumed to possess a more or less ordered hydrogen-bonding network, (C) 1997 Published by Elsevier Science B.V.

引用

页码：140 / 144

页数：5

共 27 条

[1]

[Anonymous], 1971, J APPL METEOROL, DOI DOI 10.1175/1520-0450(1971)010<1044:TBP0SA>2.0.C0

[2]

[3]

[Anonymous], 1931, COLLECTED WORKS JW G

[4] SURFACE TENSION OF IONIC SOLUTIONS .1. DERIVATION OF LIMITING LAW AT INFINITE DILUTION FROM POISSON-BOLTZMANN EQUATION [J].

BELLEMANS, A .

PHYSICA, 1964, 30 (04) :924-&

[5] SURFACE TENSION OF IONIC SOLUTIONS [J].

BUFF, FP ;

STILLINGER, FH .

JOURNAL OF CHEMICAL PHYSICS, 1956, 25 (02) :312-318

[6] HETEROGENEOUS REACTIONS IN A STRATOSPHERIC BOX MODEL - A SENSITIVITY STUDY [J].

DANILIN, MY ;

MCCONNELL, JC .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1994, 99 (D12) :25681-25696

[7] MEASUREMENT OF THE ADSORPTION OF SURFACE-ACTIVE AGENT AT A SOLUTION AIR INTERFACE BY A RADIOTRACER METHOD [J].

DIXON, JK ;

WEITH, AJ ;

ARGYLE, AA ;

SALLEY, DJ .

NATURE, 1949, 163 (4152) :845-845

[8] VIBRATIONAL-SPECTRA OF WATER-MOLECULES AT QUARTZ WATER INTERFACES [J].

DU, Q ;

FREYSZ, E ;

SHEN, YR .

PHYSICAL REVIEW LETTERS, 1994, 72 (02) :238-241

[9] VIBRATIONAL SPECTROSCOPY OF WATER AT THE VAPOR WATER INTERFACE [J].

DU, Q ;

SUPERFINE, R ;

FREYSZ, E ;

SHEN, YR .

PHYSICAL REVIEW LETTERS, 1993, 70 (15) :2313-2316

[10] VIBRATIONAL-SPECTRA OF PURE H2SO4 AND D2SO4 ACIDS IN LIQUID-STATE [J].

GOYPIRON, A ;

VILLEPIN, JD ;

NOVAK, A .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1978, 75 (09) :889-894

← 1 2 3 →