X-ray crystal structures of hexa-oxotellurate complexes of ruthenium(VI) and silver(III):: Na6[RuO2{TeO4(OH)2}2]•16H2O and Na5[Ag{TeO4(OH)2}2]•16H2O

被引：0
作者：
Hector, AL [1 ]
Hill, NJ [1 ]
Levason, W [1 ]
Webster, M [1 ]
机构：
[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2002年 / 628卷 / 04期
关键词：
tellurates; ruthenium; silver; crystal structure;
D O I：
10.1002/1521-3749(200205)628:4<815::AID-ZAAC815>3.0.CO;2-U
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
X-ray crystal structures are reported for Na-6[RuO2{TeO4(OH)(2)}(2)] . 16H(2)O and Na-5[Ag{TeO4(OH)(2)}(2)] . 16H(2)O which contain respectively Ru-VI and Ag-III coordinated to chelating bidentate tellurate ([TeO4(OH)(2)](4-)) groups. Na-6[RuO2{TeO4(OH)(2)}(2)] . 16H(2)O: Space group P(1) over bar, Z = 2. lattice dimensions at 120 K; a = 6.9865(1), b = 8.7196(2) c = 11.7395(2) Angstrom, alpha = 74.008(1), beta = 79.954(1), gamma = 88.514(1)degrees R1 = 0.025. Na-5[Ag{TeO4(OH)(2)}(2)] . 16H(2)O: Space group P(1) over bar. Z = 2, lattice dimensions at 120 K a = 5.888(1), b = 8.932(1), c = 12.561(2) Angstrom, alpha = 98.219(6), beta = 97.964(9), gamma = 93.238(14)degrees; R1 = 0.047.
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页码：815 / 818
页数：4
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