Monitoring of polycyclic aromatic hydrocarbons (PAHs) in the atmosphere of southern Luxembourg using XAD-2 resin-based passive samplers

被引：12
作者：
Schummer, Claude [1 ,2 ]
Appenzeller, Brice M. [2 ]
Millet, Maurice [1 ]
机构：
[1] Univ Strasbourg, LMSPC, UMR 7515, Equipe Physicochim Atmosphere,CNRS, F-67084 Strasbourg, France
[2] Univ Luxembourg, Lab Analyt Human Biomonitoring CRP Sante, L-1511 Luxembourg, Luxembourg
来源：
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH | 2014年 / 21卷 / 03期
关键词：
PAHs; Passive sampling; XAD-2; resin; Spatial variations; Temporal variations; Adsorption kinetics; PERSISTENT ORGANIC POLLUTANTS; POLYBROMINATED DIPHENYL ETHERS; AIR SAMPLERS; ORGANOCHLORINE PESTICIDES; POLYCHLORINATED-BIPHENYLS; SAMPLING MEDIA; EMISSION; URBAN; PCBS; CALIBRATION;
D O I：
10.1007/s11356-013-2106-y
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
XAD-2 resin-based passive samplers (PAS) with dimensions adapted to 100 mL accelerated solvent extraction cells were used to study the temporal and spatial variations of 17 PAHs on five sites in the atmosphere of southern Luxembourg. This new design allowed extracting the PAS without emptying the resin from the shelter. PAH analyses were done with gas chromatography-tandem mass spectrometry. PAS were deployed for 1 year with varying sampling periodicities, and 16 PAHs were detected with concentrations ranging from 1 ng/PAS for chrysene to 9,727 ng/PAS for naphthalene. The PAS were found adapted to the monitoring of temporal and spatial variations for lightweight PAHs (up to four aromatic rings) though not for heavy PAHs with five aromatic rings or more, as these compounds are preferably in the particle phase of the atmosphere and the amount of these PAHs trapped on the PAS will be too low.
引用
收藏
页码：2098 / 2107
页数：10
相关论文
共 35 条
[11]  
2, 10.1002/etc.5620160310]
[12]   Sorption of a diverse set of organic chemical vapors onto XAD-2 resin: Measurement, prediction and implications for air sampling [J].
Hayward, Stephen J. ;
Lei, Ying D. ;
Wania, Frank .
ATMOSPHERIC ENVIRONMENT, 2011, 45 (02) :296-302
[13]   Comparison of Four Active and Passive Sampling Techniques for Pesticides in Air [J].
Hayward, Stephen J. ;
Gouin, Todd ;
Wania, Frank .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2010, 44 (09) :3410-3416
[14]  
IARC (International Agency for Research on Cancer), 1972, IARC MON EV CARC RIS, V3
[15]   CARCINOGENICITY OF DINITROPYRENES IN THE WEANLING FEMALE CD RAT [J].
IMAIDA, K ;
LEE, MS ;
WANG, CY ;
KING, CM .
CARCINOGENESIS, 1991, 12 (07) :1187-1191
[16]  
INERIS (Institut National de l'Environnement industriel et des Risques), 2005, INERISDRC012559000DF
[17]   Passive air sampling of polycyclic aromatic hydrocarbons and polychlorinated naphthalenes across Europe [J].
Jaward, FM ;
Farrar, NJ ;
Harner, T ;
Sweetman, AJ ;
Jones, KC .
ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY, 2004, 23 (06) :1355-1364
[18]   Assessing the influence of meteorological parameters on the performance of polyurethane foam-based passive air samplers [J].
Klanova, Jana ;
Eupr, Pavel ;
Kohoutek, Jiri ;
Harner, Tom .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2008, 42 (02) :550-555
[19]   Gas-particle concentrations and distribution of aliphatic hydrocarbons, PAHs, PCBs and PCDD/Fs in the atmosphere of Athens (Greece) [J].
Mandalakis, M ;
Tsapakis, M ;
Tsoga, A ;
Stephanou, EG .
ATMOSPHERIC ENVIRONMENT, 2002, 36 (25) :4023-4035
[20]   Spatial and temporal PAH concentrations in Zaragoza, Spain [J].
Mastra, AM ;
López, JM ;
Callén, MS ;
García, T ;
Murillo, R ;
Navarro, MV .
SCIENCE OF THE TOTAL ENVIRONMENT, 2003, 307 (1-3) :111-124
1234