Syntheses, crystal structures and properties of two nickel(II) coordination polymers constructed from 5-(isonicotinamido)isophthalic acid

被引：1

作者：

Chen, Man-sheng ^{[1
]}

Deng, Yi-fang ^{[1
]}

Zhang, Chun-hua ^{[1
]}

Xu, Jin-sheng ^{[1
]}

Nie, Xue ^{[1
]}

Tang, Si-ping ^{[1
]}

机构：

[1] Hengyang Normal Univ, Dept Chem & Mat Sci, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China

来源：

TRANSITION METAL CHEMISTRY | 2013年 / 38卷 / 07期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORK; BINDING;

D O I：

10.1007/s11243-013-9744-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two Ni(II) metal-organic frameworks, [Ni(INAIP)(DMF)]center dot 0.5DMF and [Ni(INAIP)(H2O)]center dot 2H(2)O, have been synthesized by the reaction of 5-(isonicotinamido)isophthalic acid (H(2)INAIP) with NiSO4 center dot 6H(2)O using different reaction solvents. Single-crystal X-ray diffraction analysis indicates that [Ni(INAIP)(DMF)]center dot 0.5DMF has a twofold interpenetrated three-dimensional (3D) framework with sra topology, while [Ni(INAIP)(H2O)]center dot 2H(2)O has a two-dimensional (2D) network structure with a 4-connected (4(3)center dot 6(3)) topology. In addition, the magnetic and adsorption properties of the complexes were explored.

引用

页码：745 / 750

页数：6

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