A combined photolytic-electrolytic system for the simultaneous recovery of copper and degradation of phenol or 4-chlorophenol in mixed solutions

被引：18

作者：

Chaudhary, Abdul J. ^{[1
]}

Grimes, Susan M. ^{[2
]}

机构：

[1] Brunel Univ, Inst Environm, Uxbridge UB8 3PH, Middx, England

[2] Univ London Imperial Coll Sci Technol & Med, Dept Civil & Environm Engn, Ctr Environm Control & Waste Managment, London SW7 2AZ, England

来源：

CHEMOSPHERE | 2008年 / 72卷 / 11期

基金：

英国工程与自然科学研究理事会;

关键词：

copper recovery; degradation of phenols; electrolytic cell; photolytic cell; combined photolytic-electrolytic cell; wastewater treatment;

D O I：

10.1016/j.chemosphere.2008.05.048

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The effects of the presence of copper on the photooxidation of phenol and 4-chlorophenol and of the presence of the phenols on the recovery of copper by electrodeposition are studied in three systems: a photolytic cell in the presence and absence of TiO2 as a catalyst or H2O2 as an oxidant; an electrolytic cell and a combined photolytic-electrolytic system. The optimum system for the simultaneous removal of copper and destruction of the phenols which overcomes the effects of copper-phenol reactions is a combined system with concentrator electrode technology incorporated into the electrolytic cell. This combined system achieves > 99% removal of copper and destruction of phenol or 4-chlorophenol in an 8 h period. (c) 2008 Elsevier Ltd. All rights reserved.

引用

页码：1636 / 1642

页数：7

共 17 条

[1] The influence of residence time on the anodic oxidation of phenol [J].

Awad, YM ;

Abuzaid, NS .

SEPARATION AND PURIFICATION TECHNOLOGY, 2000, 18 (03) :227-236

[2] THE INFLUENCE OF DISSOLVED METAL-IONS ON THE PHOTOCATALYTIC DEGRADATION OF PHENOL IN AQUEOUS TIO2 SUSPENSIONS [J].

BREZOVA, V ;

BLAZKOVA, A ;

BOROSOVA, E ;

CEPPAN, M ;

FIALA, R .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 98 (02) :109-116

[3] Simultaneous recovery of copper and degradation of 2,4-dichlorophenoxyacetic acid in aqueous systems by a combination of electrolytic and photolytic processes [J].

Chaudhary, AJ ;

Grimes, SM ;

Mukhtar-ul-Hassan, M .

CHEMOSPHERE, 2001, 44 (05) :1223-1230

[4]

Chaudhary AJ, 2000, J CHEM TECHNOL BIOT, V75, P353, DOI 10.1002/(SICI)1097-4660(200005)75:5<353::AID-JCTB221>3.0.CO

[5]

2-Y

[6] Comparison of different advanced oxidation processes for phenol degradation [J].

Esplugas, S ;

Giménez, J ;

Contreras, S ;

Pascual, E ;

Rodríguez, M .

WATER RESEARCH, 2002, 36 (04) :1034-1042

[7] Comparison of phenol and 4-chlorophenol adsorption in activated carbon with different physical properties [J].

García-Mendieta, A ;

Solache-Ríos, M ;

Olguín, MT .

SEPARATION SCIENCE AND TECHNOLOGY, 2003, 38 (11) :2549-2564

[8] Simultaneous recovery of metals and destruction of organic species: Cobalt and phthalic acid [J].

Grimes, SM ;

Donaldson, JD ;

Chaudhary, AJ ;

Hassan, MU .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2000, 34 (19) :4128-4132

[9]

Grimes SM, 2000, J AOAC INT, V83, P584

[10]

Kartal ÖE, 2001, CHEM ENG TECHNOL, V24, P645, DOI 10.1002/1521-4125(200106)24:6<645::AID-CEAT645>3.0.CO

← 1 2 →