Highly Active Dizinc Catalyst for the Copolymerization of Carbon Dioxide and Cyclohexene Oxide at One Atmosphere Pressure

被引：280

作者：

Kember, Michael R. ^{[1
]}

Knight, Paul D. ^{[1
]}

Reung, Palarp T. R. ^{[1
]}

Williams, Charlotte K. ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 05期

基金：

英国工程与自然科学研究理事会;

关键词：

carbon dioxide; macrocyclic ligands; polymerization; zinc; DIIMINATE ZINC CATALYSTS; ALTERNATING COPOLYMERIZATION; PHOSPHINE ADDUCTS; CO2; COMPLEXES; EPOXIDES; POLYMERIZATION; PORPHYRIN;

D O I：

10.1002/anie.200803896

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Low-pressure catalyst: A novel dizinc complex (1) having a macrocyclic ancillary ligand shows remarkable activity for the copolymerization of carbon dioxide and cyclohexene oxide, at only one atmosphere of CO2. TON=turnover number; TOF=turnover frequency. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：931 / 933

页数：3

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