All-solid-state lithium ion battery using garnet-type oxide and Li3BO3 solid electrolytes fabricated by screen-printing

被引：326
作者：
Ohta, Shingo [1 ]
Komagata, Shogo [1 ]
Seki, Juntaro [1 ]
Saeki, Tohru [1 ]
Morishita, Shinya [1 ]
Asaoka, Takahiko [1 ]
机构：
[1] Toyota Cent Res & Dev Labs Inc, Battery & Cells Div, Nagakute, Aichi 4801192, Japan
来源：
JOURNAL OF POWER SOURCES | 2013年 / 238卷
关键词：
Lithium ion secondary battery; All-solid-state lithium ion battery; Solid oxide electrolyte; Electrochemical performance; Solid state reaction; SECONDARY BATTERIES; CONDUCTIVITY; LI7LA3ZR2O12; LICOO2; COMPATIBILITY; PERFORMANCE; GLASSES; ANODE; X=0-2; BA;
D O I：
10.1016/j.jpowsour.2013.02.073
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
An all-solid-state lithium ion battery was constructed with a screen-printing process using Nb doped Li7La3Zr2O12 (LLZONb) as the solid electrolyte and Li3BO3 (LBO) as a solid electrolyte within the cathode layer. LBO is a lithium ion conductor that is chemically stable with the LiCoO2 (LCO) active cathode material and LLZONb. Sufficient interface contact between the cathode layer and the LLZONb solid electrolyte can be easily achieved with sintering LBO into the cathode layer by an annealing process. The resultant battery exhibited good electrochemical performance and a lower interfacial resistance comparable with that of lithium ion batteries with liquid organic electrolytes. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：53 / 56
页数：4
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