Carborane-functionalized polyaza aromatic ligands: Synthesis, crystal structure, and a copper(II) complex

被引：39
作者：
Prokhorov, Anton M.
Kozhevnikov, Dmitry N.
Rusinov, Vladimir L.
Chupakhin, Oleg N.
Glukhov, Ivan V.
Antipin, Mikhail Yu.
Kazheva, Olga N.
Chekhlov, Anatolii N.
Dyachenko, Oleg A.
机构：
[1] Urals State Tech Univ, Ekaterinburg 620002, Russia
[2] Russian Acad Sci, Inst Organ Synth, Ural Branch, Ekaterinburg 620219, Russia
[3] Russian Acad Sci, Inst Organoelement Cpds, Xray Crystallog Lab, Moscow 119991, Russia
[4] Russian Acad Sci, Inst Problem Chem Phys, Xray Crystallog Lab, Chernogolovka 142432, Russia
来源：
ORGANOMETALLICS | 2006年 / 25卷 / 12期
关键词：
D O I：
10.1021/om051058v
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A consecutive aromatic nucleophilic substitutions of hydrogen in 1,2,4-triazine4-oxides and an aza Diels-Alder reaction is a versatile route to carborane-functionalized bi- and terpyridines and their 1,2,4-triazine analogues. The heterocycles facilitate deboronation of the substituted carboranes, and the carborane moiety has a significant influence on the coordination properties of the ligands as well.
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页码：2972 / 2977
页数：6
相关论文
共 28 条
[1]  
[Anonymous], 2015, Acta Crystallogr., V71, P3
[2]  
[Anonymous], [No title captured]
[3]   Carboranyl cluster-functionalised ligands for metallosupramolecular chemistry [J].
Armspach, D ;
Constable, EC ;
Housecroft, CE ;
Neuburger, M ;
Zehnder, M .
SUPRAMOLECULAR CHEMISTRY, 1996, 7 (02) :97-100
[4]  
Armspach D, 1996, NEW J CHEM, V20, P331
[5]   Carbaborane-functionalised 2,2′:6′,2"-terpyridine ligands for metallosupramolecular chemistry:: Syntheses, complex formation, and the crystal and molecular structures of 4′-(optho-carboranyl)-2,2′:6′,2"-terpyridine and 4′-(ortho-carboranylpropoxy)-2,2′:6′,2"-terpyridine [J].
Armspach, D ;
Constable, EC ;
Housecroft, CE ;
Neuburger, M ;
Zehnder, M .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 550 (1-2) :193-206
[6]  
BEAUDET RA, 1988, ADV BORON BORANES, P417
[7]   A facile S-transalkylation of 2,2′-bipyridine alkyl sulfides -: a new tool for the synthesis of annulated biheterocycles [J].
Branowska, D ;
Rykowski, A ;
Wysocki, W .
TETRAHEDRON LETTERS, 2005, 46 (37) :6223-6226
[8]   Chiral 2,2′-bipyridines, 1,10-phenanthrolines, and 2,2′:6′,2"-terpyridines:: Syntheses and applications in asymmetric homogeneous catalysis [J].
Chelucci, G ;
Thummel, RP .
CHEMICAL REVIEWS, 2002, 102 (09) :3129-3170
[9]   Lithiacarboranes and 1,2,4-triazine 4-oxides:: SNH reactions and ring transformations [J].
Chupakhin, ON ;
Prokhorov, AM ;
Kozhevnikov, DN ;
Rusinova, VL ;
Glukhov, IA ;
Starikova, ZA ;
Ol'shevskaya, VA ;
Kalinin, VN ;
Antipin, MY .
RUSSIAN CHEMICAL BULLETIN, 2004, 53 (06) :1223-1231
[10]   HIGHER OLIGOPYRIDINES AS A STRUCTURAL MOTIF IN METALLOSUPRAMOLECULAR CHEMISTRY [J].
CONSTABLE, EC .
PROGRESS IN INORGANIC CHEMISTRY, VOL 42, 1994, 42 :67-138
123