Di-μ-chlorido-bis[(2,2′-bibenzimidazole)chloridocadmium(II)]

被引：5

作者：

Liu, Ge ^{[1
]}

机构：

[1] Chifeng Univ, Chifeng 024000, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

D O I：

10.1107/S1600536808040968

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title binuclear complex, [Cd(2)Cl(4)(C(14)H(10)N(4))(2)], was synthesized by the hydrothermal reaction of CdCl(2) and the ligand 2,2'-bibenzimidazole. The molecule lies on an inversion center and the metal center displays a strongly distorted trigonal-bipyramidal geometry. The Cd(II) ions are coordinated by two N atoms from the organic ligand, and by one terminal and two bridging chloride anions. The crystal structure involves intermolecular N-H center dot center dot center dot Cl hydrogen bonds, resulting in a one-dimensional supramolecular structure.

引用

页码：M37 / U457

页数：10

共 5 条

[1] MOLECULAR-STRUCTURE OF MU-PYRAZOLE-BIS(ETA5-CYCLOPENTADIENYL)TITANIUM(III), A DIMERIC TITANIUM(III) COMPOUND WITH A BRIDGING ORGANIC GROUP [J].