Experimental Measurements of Hydrate Phase Equilibria for Carbon Dioxide in the Presence of THF, Propylene Oxide, and 1,4-Dioxane

被引：74

作者：

Seo, Yutaek ^{[2
]}

Kang, Seong-Pil ^{[2
]}

Lee, Sangyong ^{[3
]}

Lee, Huen ^{[1
]}

机构：

[1] Korea Adv Inst Sci & Technol, Dept Chem & Biomol Engn, Taejon 305701, South Korea

[2] Korea Inst Energy Res, Taejon 305343, South Korea

[3] Texas A&M Univ, Dept Chem & Nat Gas Engn, Kingsville, TX 78363 USA

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2008年 / 53卷 / 12期

关键词：

D O I：

10.1021/je800566y

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Hydrate phase equilibria have been measured for carbon dioxide + cyclic ethers + water in the temperature range of (270 to 290) K and in the pressure range of (0.2 to 4.7) MPa. Three cyclic ethers, THF, propylene oxide, and 1,4-dioxane, were selected at a mole fraction of 0.03. The stabilization effect of the mixed hydrate was found to be the highest for THF followed by propylene oxide, while no stabilization effect was observed for 1,4-dioxane in the studied temperature and pressure range. The mole fraction effect on hydrate phase equilibria has also been investigated for THF and propylene oxide in the range of x = (0.01 to 0.10).

引用

页码：2833 / 2837

页数：5

共 48 条

[21] Semi-clathrate hydrate phase equilibria of carbon dioxide in presence of tetra-n-butyl-ammonium chloride (TBAC): Experimental measurements and thermodynamic modeling [J].

Momeni, Kamalodin ;

Jomekian, Abolfazl ;

Bazooyar, Bahamin .

FLUID PHASE EQUILIBRIA, 2020, 508

[22] Experimental measurements and modelling of carbon dioxide hydrate phase equilibrium with and without ethanol [J].

Ferrari, Paolo F. ;

Guembaroski, Amanda Z. ;

Marcelino Neto, Moises A. ;

Morales, Rigoberto E. M. ;

Sum, Amadeu K. .

FLUID PHASE EQUILIBRIA, 2016, 413 :176-183

[23] Clathrate hydrate formation of CO2 in the presence of water miscible (1,4-dioxane) and partially water miscible (cyclopentane) organic compounds: Experimental measurement and thermodynamic modeling [J].

Pahlavanzadeh, Hassan ;

Mohammadi, Amir H. ;

Jokandan, Behbood Azizi ;

Farhoudi, Ali .

JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING, 2019, 179 :465-473

[24] Isothermal vapor-liquid equilibria in the binary 1,4-dioxane plus ethylene glycol system. I - Experimental data [J].

Omota, LM ;

Iulian, O ;

Iliuta, MC .

REVUE ROUMAINE DE CHIMIE, 2001, 46 (03) :255-258

[25] Thermodynamic modeling of pressure-temperature phase diagrams of binary clathrate hydrates of methane, carbon dioxide or nitrogen plus tetrahydrofuran, 1,4-dioxane or acetone [J].

Pahlavanzadeh, Hassan ;

Kamran-Pirzaman, Arash ;

Mohammadi, Amir H. .

FLUID PHASE EQUILIBRIA, 2012, 320 :32-37

[26] Experimental measurement of gas hydrate phase equilibria in the CO2+TBPB + THF system in the presence and absence of NaCl aqueous solution [J].

Ghavi, Amirreza ;

Pahlavanzadeh, Hassan ;

Eslamimanesh, Ali .

FLUID PHASE EQUILIBRIA, 2024, 576

[27] Density and refractive index measurements of critical mixture 1,4-dioxane + water plus saturated KCl in homogenous phase region [J].

Kouissi, T. ;

Bouanz, M. .

FLUID PHASE EQUILIBRIA, 2010, 293 (01) :79-86

[28] Mechanisms of 1,4-Dioxane Biodegradation and Adsorption by Bio-Zeolite in the Presence of Chlorinated Solvents: Experimental and Molecular Dynamics Simulation Studies [J].

Liu, Yun ;

Johnson, Nicholas W. ;

Liu, Cun ;

Chen, Ruihuan ;

Zhong, Ming ;

Dong, Yuanhua ;

Mahendra, Shaily .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2019, 53 (24) :14538-14547

[29] Experimental Phase Equilibria of Carbon Dioxide and Methane Hydrates in the Presence of 2-Propanol and Sodium Chloride [J].

de Vasconcelos, Luiz Fernando S. ;

Kakitani, Celina ;

Neto, Moises A. Marcelino ;

Morales, Rigoberto E. M. .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2022, 67 (06) :1528-1540

[30] Experimental Measurements for Equilibrium Conditions of Carbon Dioxide Hydrate Mixtures with Each Additive of 1,3-Dioxane, Acetamide, Cyclopentanol, Cyclopentanone, or 1,3,5-Trioxane [J].

Tang, Muoi ;

Wang, Hsin-Wei ;

Wu, Yi-Ping ;

Tsai, Jung-Chin ;

Chen, Yan-Ping .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2022, 67 (10) :2954-2962

← 1 2 3 4 5 →