The Reaction and Materials Chemistry of [Sn6(O)4(OSiMe3)4]: Chemical Vapour Deposition of Tin Oxide

被引：23

作者：

Barbul, Ioana ^{[2
]}

Johnson, Andrew L. ^{[1
]}

Kociok-Koehn, Gabriele ^{[1
]}

Molloy, Kieran C. ^{[1
]}

Silvestru, Christian ^{[2
]}

Sudlow, Anna L. ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[2] Univ Babes Bolyai, Fac Chim & Ingn Chim, Ctr Chim Supramol Organ & Organomet CCSOOM, Dept Chim, Cluj Napoca 400028, Romania

来源：

CHEMPLUSCHEM | 2013年 / 78卷 / 08期

关键词：

chemical vapor deposition; cluster compounds; bridging ligands; thin films; tin; CRYSTAL-STRUCTURE; SNO; TIN(II); DISPROPORTIONATION; HYDROLYSIS; ALKOXIDES;

D O I：

10.1002/cplu.201300104

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Sn-6(O)(4)(OSiMe3)(4)] and [{Sn(OSiMe3)(2)}(2)] have been used to deposit SnO thin films by chemical vapour deposition. Films derived from [Sn-6(O)(4)(OSiMe3)(4)] comprise uniform cubes and are highly oriented, whereas those deposited from [{Sn(OSiMe3)(2)}(2)] are made up of a continuous non-oriented layer with oriented cubes on the surface. The structure of a co-crystal, 2Sn(6)(O)(4)(OSiMe3)(4)[Sn(OSiMe3)(2)](2)4THF, shows that [{Sn(OSiMe3)(2)}(2)], a liquid at room temperature, adopts a -OSiMe3-bridged dimeric structure. [Sn-6(O)(4)(OSiMe3)(4)] reacts with O-2 in a controlled manner to afford the novel oxo-cluster [Sn4(O)(OSiMe3)(8)], the structure of which is reported. In addition, a crystal of {[Sn-4(O)(OSiMe3)(5)](+)(2)[Sn(O)(OSiMe3)(4)Cl](+)(2)}[Cl](-)(4) has been fortuitously isolated from the presence of SnCl2 in the starting material for the preparation of [Sn-6(O)(4)(OSiMe3)(4)], and has been shown to incorporate two novel cationic oxo-tin clusters.

引用

页码：866 / 874

页数：9

共 36 条

[1] Nanoparticles of SnO produced by sonochemistry as anode materials for rechargeable lithium batteries [J].

Aurbach, D ;

Nimberger, A ;

Markovsky, B ;

Levi, E ;

Sominski, E ;

Gedanken, A .

CHEMISTRY OF MATERIALS, 2002, 14 (10) :4155-4163

[2] Recent developments in the emerging field of crystalline p-type transparent conducting oxide thin films [J].

Banerjee, AN ;

Chattopadhyay, KK .

PROGRESS IN CRYSTAL GROWTH AND CHARACTERIZATION OF MATERIALS, 2005, 50 (1-3) :52-105

[3] Hydrolysis of in(II) neo-pentoxide:: Syntheses, characterization, and X-ray structures of [Sn(ONeP)2]∞, Sn5(μ3-O)2(μ-ONeP)6, and Sn6(μ3-O)4(μ-ONeP)4 where ONeP = OCH2CMe3 [J].

Boyle, TJ ;

Alam, TM ;

Rodriguez, MA ;

Zechmann, CA .

INORGANIC CHEMISTRY, 2002, 41 (09) :2574-2582

[4]

Farrugia L. J., 1999, Journal of Applied Crystallography, V32, P837, DOI [DOI 10.1107/S0021889812029111, 10.1107/S0021889899006020, DOI 10.1107/S0021889899006020]

[5] CHEMISTRY OF BULKY ALKOXIDES OF BIVALENT GERMANIUM AND TIN - STRUCTURES OF GASEOUS [SN(OBUT)2]2 AND CRYSTALLINE GE(OCBUT3)2 [J].

FJELDBERG, T ;

HITCHCOCK, PB ;

LAPPERT, MF ;

SMITH, SJ ;

THORNE, AJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (14) :939-941

[6] X-RAY-DIFFRACTION AND MOSSBAUER ANALYSES OF SNO DISPROPORTIONATION PRODUCTS [J].

GAUZZI, F ;

VERDINI, B ;

MADDALENA, A ;

PRINCIPI, G .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 104 (01) :1-7

[7] Kinetics of the disproportionation of SnO [J].

Giefers, H ;

Porsch, F ;

Wortmann, G .

SOLID STATE IONICS, 2005, 176 (1-2) :199-207

[8] Criteria for choosing transparent conductors [J].

Gordon, RG .

MRS BULLETIN, 2000, 25 (08) :52-57

[9] WINDOW COATINGS FOR THE FUTURE [J].

GRANQVIST, CG .

THIN SOLID FILMS, 1990, 193 (1-2) :730-741

[10] Transparent conductors as solar energy materials: A panoramic review [J].

Granqvist, Claes G. .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2007, 91 (17) :1529-1598

← 1 2 3 4 →