New copper(II) complexes produced by the template reaction of acetoacetic-2-pyridylamide and amino-aliphatic alcohols

被引：30
作者：
ElTabl, AS
Imam, SM
机构：
[1] Department of Chemistry, Faculty of Science, Menofia University, Shebin El-Kom
来源：
TRANSITION METAL CHEMISTRY | 1997年 / 22卷 / 03期
关键词：
D O I：
10.1023/A:1018464508113
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The template condensation of acetoacetic-2-pyridylamide with amino aliphatic alcohols such as 2-aminoethanol (HL1) and 3-amino propanol (HL2) in the presence of copper(II) ions gave octahedral complexes, which have been characterized by elemental analyses, u.v.-vis. and i.r. spectra, conductivity, d.t.a, magnetic and e.s.r. measurements. The molar conductance in DMF indicate that the complexes are non-ionic in character. The e.s.r. spectra of solid complexes (2) and (5) at room temperature indicate axial type symmetry (d(x2-y2)) With covalent bond character.
引用
收藏
页码：259 / 262
页数：4
相关论文
共 33 条
[1]   COBALT(II) AND COPPER(II) COMPLEXES WITH BENZOYL AND SALICOYL HYDRAZONES DERIVED FROM BETA-DIKETONES [J].
ABUELWAFA, SM ;
SALIB, KAR ;
ELINANY, G ;
ISMAIL, TM .
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1990, 20 (10) :1343-1354
[2]   POLYNUCLEAR COMPLEXES WITH HYDROGEN-BONDED BRIDGES - DINUCLEAR COMPLEX OF N,N'-BIS(2-HYDROXYETHYL)-2,4-PENTANEDIIMINE WITH COPPER(II) [J].
BERTRAND, JA ;
BLACK, TD ;
ELLER, PG ;
HELM, FT ;
MAHMOOD, R .
INORGANIC CHEMISTRY, 1976, 15 (12) :2965-2970
[3]   CU(II) AND PD(II) COMPLEXES WITH ADENINE AND HISTIDINE DERIVATIVES [J].
DANOPOULOS, AA ;
PARASKEWAS, SM .
INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1981, 55 (05) :141-145
[4]   EFFECT OF EXCHANGE INTERACTION ON THE MAGNETIC AND THERMAL PROPERTIES OF COPPER SALTS AND COPPER COORDINATION COMPOUNDS [J].
EISENSTEIN, JC .
JOURNAL OF CHEMICAL PHYSICS, 1958, 28 (02) :323-329
[5]  
El-Tabl A.S., 1993, THESIS MENOUFIA U EG
[6]  
ELTABI AS, 1987, THESIS MENOUFIA U EG
[7]  
ELTABL AS, 1996, TRANSIT METAL CHEM, V21, P1
[8]   METAL-COMPLEXES OF SOME TETRAKETONES AND THEIR SCHIFF-BASES [J].
FENTON, DE ;
TATE, JR ;
CASELLATO, U ;
TAMBURINI, S ;
VIGATO, PA ;
VIDALI, M .
INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1984, 83 (01) :23-31
[9]   SYNTHESIS, THERMAL AND ELECTRICAL STUDIES ON ZIRCONYL COMPLEXES WITH SCHIFF-BASES DERIVED FROM 2-HYDROXY-1-NAPHTHALDEHYDE AND SOME AROMATIC DIAMINES [J].
GABER, M ;
AYAD, MM ;
AYAD, MI .
THERMOCHIMICA ACTA, 1991, 176 :21-29
[10]   USE OF CONDUCTIVITY MEASUREMENTS IN ORGANIC SOLVENTS FOR CHARACTERISATION OF COORDINATION COMPOUNDS [J].
GEARY, WJ .
COORDINATION CHEMISTRY REVIEWS, 1971, 7 (01) :81-&
1234