Soluble Conjugated Microporous Polymers

被引：200
作者：
Cheng, Ge [1 ,2 ]
Hasell, Tom [1 ,2 ]
Trewin, Abbie [1 ,2 ]
Adams, Dave J. [1 ,2 ]
Cooper, Andrew I. [1 ,2 ]
机构：
[1] Univ Liverpool, Dept Chem, Liverpool L69 3BX, Merseyside, England
[2] Univ Liverpool, Ctr Mat Discovery, Liverpool L69 3BX, Merseyside, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 51期
基金：
英国工程与自然科学研究理事会;
关键词：
absorption; dendrimers; membranes; polymers; selectivity; INTRINSIC MICROPOROSITY; SURFACE-AREA; NETWORKS; FRAMEWORKS; OCTAVINYLSILSESQUIOXANE;
D O I：
10.1002/anie.201205521
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Soluble and porous: Soluble conjugated microporous polymers (SCMPs) can be prepared by synthesizing discrete hyperbranched molecules. The materials can be cast from solution as thin films (see picture), suggesting a range of processing options that are not available for insoluble CMP networks. Soluble, conjugated dendrimers are porous and give insight into the structural origin of microporosity. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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收藏
页码：12727 / 12731
页数：5
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