Chemoenzymatic Total Synthesis and Reassignment of the Absolute Configuration of Ribisin C

被引：14

作者：

Lan, Ping ^{[1
]}

Banwell, Martin G. ^{[1
]}

Ward, Jas S. ^{[1
]}

Willis, Anthony C. ^{[1
]}

机构：

[1] Australian Natl Univ, Inst Adv Studies, Res Sch Chem, Canberra, ACT 0200, Australia

来源：

ORGANIC LETTERS | 2014年 / 16卷 / 01期

基金：

澳大利亚研究理事会;

关键词：

FUNGUS PHELLINUS-RIBIS; CHEMICAL-SYNTHESIS; NATURAL-PRODUCTS; RING; CIS-1,2-DIHYDROCATECHOLS; DIBENZOFURANS;

D O I：

10.1021/ol403220t

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The enantiomerically pure and enzymatically derived cis-1,2-dihydrocatechol 5 has been converted, by two related pathways, into compounds 3 and ent-3. As a result, it has been determined that the true structure of the natural product ribisin C is represented by ent-3.

引用

页码：228 / 231

页数：4

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