Durable superhydrophobic paper enabled by surface sizing of starch-based composite films

被引:58
作者
Chen, Gang [1 ]
Zhu, Penghui [1 ]
Kuang, Yudi [1 ]
Liu, Yu [1 ]
Lin, Donghan [1 ]
Peng, Congxing [1 ]
Wen, Zhicheng [1 ]
Fang, Zhiqiang [1 ]
机构
[1] South China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Guangdong, Peoples R China
基金
中国博士后科学基金;
关键词
Surface sizing; Cassava starch; Superhydrophobic paper; Silica nanoparticle; Durability; WATER; ROBUST; TRANSPARENT; COATINGS; SIO2;
D O I
10.1016/j.apsusc.2017.02.201
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Superhydrophobic paper with remarkable durability is of considerable interest for its practical applications. In this study, a scalable, inexpensive, and universal surface sizing technique was implemented to prepare superhydrophobic paper with enhanced durability. A thin layer of starch-based composite, acting as a bio-binder, was first coated onto the paper surface by a sophisticated manufacturing technique called surface sizing, immediately followed by a spray coating of hexamethyl disilazane treated silica nanoparticles (HMDS-SiNPs) dispersed in ethanol on the surface of the wet starch-coated sheet, and the dual layers dried at the same time. Consequently, durable superhydrophobic paper with bi-layer structure was obtained after air drying. The as-prepared superhydrophobic paper not only exhibited a self-cleaning behavior, but also presented an enhanced durability against scratching, bending/deformation, as well as moisture. The universal surface sizing of starch-based composites may pave the way for the up-scaled and cost-effective production of durable superhydrophobic paper. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:45 / 51
页数:7
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